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タイトル: | High-Resolution Observation of Crystal Transformation in Isotactic Polybutene-1 Single Crystals (STATES AND STRUCTURES-Polymer Condensed States) |
著者: | Tosaka, Masatoshi ![]() ![]() ![]() Kamijo, Takashi Tsuji, Masaki Kohjiya, Shinzo |
キーワード: | Transmission electron microscopy Lattice fringes Image processing Nucleation Molecular mechanism |
発行日: | Mar-2001 |
出版者: | Institute for Chemical Research, Kyoto University |
誌名: | ICR Annual Report |
巻: | 7 |
開始ページ: | 8 |
終了ページ: | 9 |
抄録: | The crystal transformation in lamellar crystals of polybutene-1 grown from an amyl acetate solution was studied by cryogenic high-resolution transmission electron microscopy. The shape of the transformed trigonal (form-1) crystal domains in the surrounding tetragonal (form-2) crystal was successfully revealed. Along with the nucleation of "untwinned" form-1, the existence of another nucleation mechanism which creates "twinned" form-1 was suspected. The growth of form-1 crystal was thought to progress not stem by stem but by pulling in the molecular chains from the surrounding form-2, creating new stems of form-1. The shape of the form-1 domain was irregular, and no specific crystallographic direction along which the form-1 domain tends to grow was found. |
URI: | http://hdl.handle.net/2433/65287 |
出現コレクション: | Vol.7 (2000) |
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