Oxidation of Nickel in AlCl3-1-Butylpyridinium Chloride at Ambient Temperature

Nakaya, K.; Nakata, A.; Hirai, T.; Ogumi, Z.

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http://hdl.handle.net/2433/196780

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DCフィールド	値	言語
dc.contributor.author	Nakaya, K.	en
dc.contributor.author	Nakata, A.	en
dc.contributor.author	Hirai, T.	en
dc.contributor.author	Ogumi, Z.	en
dc.contributor.alternative	平井, 敏郎	ja
dc.date.accessioned	2015-04-03T07:05:51Z	-
dc.date.available	2015-04-03T07:05:51Z	-
dc.date.issued	2014-11-13	-
dc.identifier.issn	0013-4651	-
dc.identifier.uri	http://hdl.handle.net/2433/196780	-
dc.description.abstract	We have studied in detail the electrochemical reaction of nickel in several kinds of molar ratio-controlled molten salts consisting of AlCl(3) and 1-butylpyridinium chloride (BPC) at 40°C. We observed NiCl(2) as an oxidation product from nickel on the surface of the electrode in slightly acidic AlCl(3)/BPC salts with molar ratios of 1.05/1.0 and 1.1/1.0. However, in strongly acidic salt with the ratio of 1.5/1.0, NiCl(2) deposits on the electrode less than when in the above salts, and no NiCl(29) is observed in basic and neutral salts with the ratio of 1.0/1.0 or less AlCl(3) content. This suggests that [NiCl(4)](2−) ions form as the oxidation of nickel in such neutral and basic AlC(3)/BPC (salts).	en
dc.format.mimetype	application/pdf	-
dc.language.iso	eng	-
dc.publisher	Electrochemical Society	en
dc.rights	© The Author(s) 2014. Published by ECS.	en
dc.rights	This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited.	en
dc.title	Oxidation of Nickel in AlCl3-1-Butylpyridinium Chloride at Ambient Temperature	en
dc.type	journal article	-
dc.type.niitype	Journal Article	-
dc.identifier.ncid	AA00697016	-
dc.identifier.jtitle	Journal of the Electrochemical Society	en
dc.identifier.volume	162	-
dc.identifier.issue	1	-
dc.identifier.spage	D42	-
dc.identifier.epage	D48	-
dc.relation.doi	10.1149/2.0401501jes	-
dc.textversion	publisher	-
dcterms.accessRights	open access	-
出現コレクション:	学術雑誌掲載論文等

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