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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| acs.inorgchem.6b03028.pdf | 2.07 MB | Adobe PDF | 見る/開く |
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| DCフィールド | 値 | 言語 |
|---|---|---|
| dc.contributor.author | Haraguchi, Yuya | en |
| dc.contributor.author | Michioka, Chishiro | en |
| dc.contributor.author | Ishikawa, Manabu | en |
| dc.contributor.author | Nakano, Yoshiaki | en |
| dc.contributor.author | Yamochi, Hideki | en |
| dc.contributor.author | Ueda, Hiroaki | en |
| dc.contributor.author | Yoshimura, Kazuyoshi | en |
| dc.contributor.alternative | 原口, 祐哉 | ja |
| dc.contributor.alternative | 道岡, 千城 | ja |
| dc.contributor.alternative | 石川, 学 | ja |
| dc.contributor.alternative | 中野, 義明 | ja |
| dc.contributor.alternative | 矢持, 秀起 | ja |
| dc.contributor.alternative | 植田, 浩明 | ja |
| dc.contributor.alternative | 吉村, 一良 | ja |
| dc.date.accessioned | 2017-04-05T06:16:42Z | - |
| dc.date.available | 2017-04-05T06:16:42Z | - |
| dc.date.issued | 2017-02-10 | - |
| dc.identifier.issn | 0020-1669 | - |
| dc.identifier.uri | http://hdl.handle.net/2433/219444 | - |
| dc.description.abstract | We grew large single crystals of the cluster magnet Nb3Cl8 with a magnetic triangular lattice and investigated its magnetic properties and crystal structure. In Nb3Cl8, the [Nb3]8+ cluster has a single unpaired spin, making it an S = 1/2 triangular lattice anti-ferromagnet. At low temperatures, Nb3Cl8 exhibits a magnetic–nonmagnetic phase transition driven by a charge disproportionation, in which the paramagnetic [Nb3]8+ clusters transform into alternating layers of nonmagnetic [Nb3]7+ and [Nb3]9+ clusters. The observed exotic phenomenon with the strong correlation between the magnetism and structure are based on the nature of the cluster magnetism. | en |
| dc.format.mimetype | application/pdf | - |
| dc.language.iso | eng | - |
| dc.publisher | American Chemical Society (ACS) | en |
| dc.rights | This document is the Accepted Manuscript version of a Published Work that appeared in final form in 'Inorganic Chemistry', copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://doi.org/10.1021/acs.inorgchem.6b03028. | en |
| dc.rights | The full-text file will be made open to the public on 10 February 2018 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. | en |
| dc.rights | この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | ja |
| dc.rights | This is not the published version. Please cite only the published version. | en |
| dc.title | Magnetic–Nonmagnetic Phase Transition with Interlayer Charge Disproportionation of Nb3 Trimers in the Cluster Compound Nb3Cl8 | en |
| dc.type | journal article | - |
| dc.type.niitype | Journal Article | - |
| dc.identifier.jtitle | Inorganic Chemistry | en |
| dc.identifier.volume | 56 | - |
| dc.identifier.issue | 6 | - |
| dc.identifier.spage | 3483 | - |
| dc.identifier.epage | 3488 | - |
| dc.relation.doi | 10.1021/acs.inorgchem.6b03028 | - |
| dc.textversion | author | - |
| dc.identifier.pmid | 28240540 | - |
| dcterms.accessRights | open access | - |
| datacite.date.available | 2018-02-10 | - |
| datacite.awardNumber | 16H04131 | - |
| datacite.awardNumber | 26410089 | - |
| datacite.awardNumber | 16J04048 | - |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
| jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
| jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
| 出現コレクション: | 学術雑誌掲載論文等 | |
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