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タイトル: | Reinvestigation of the Phase Equilibria in the La_2O_3-P_2O_5 System |
著者: | Hatada, Naoyuki Nagai, Takashi Nose, Yoshitaro https://orcid.org/0000-0002-8320-1953 (unconfirmed) Uda, Tetsuya |
著者名の別形: | 畑田, 直行 宇田, 哲也 |
キーワード: | lanthanum phosphate phase diagram solid state reaction |
発行日: | Jun-2013 |
出版者: | ASM International |
誌名: | Journal of Phase Equilibria and Diffusion |
巻: | 34 |
号: | 3 |
開始ページ: | 196 |
終了ページ: | 201 |
抄録: | The phase equilibria between the solid phases in the La_2O_3-P_2O_5 system were reinvestigated with solid state reaction method. The existence of La_3PO_7, La_7P_3O_{18}, LaPO_4, and LaP_3O_9 was confirmed. La_7P_3O_{18} can form only at ~1200℃ or higher possibly due to kinetic reasons, but it is stable at lower temperatures. On the other hand, three intermediate compounds proposed to exist, La_5PO_10, La_4(P_2O_7)_3, and La_2P_4O_{13} were not obtained in this study. Based on the literature, La_4(P_2O_7)_3 and La_2P_4O_{13} are considered to be metastable phases, although thermodynamic evidence is still required. |
著作権等: | © 2013 ASM International. This paper was published in Journal of Phase Equilibria and Diffusion, Vol.34, Issue 3, pp. 196-201 and is made available as an electronic reprint with the permission of ASM International. One print or electronic copy may be made for personal use only. Systematic or multiple reproduction, distribution to multiple locations via electronic or other means, duplications of any material in this paper for a fee or for commercial purposes, or modification of the content of this paper are prohibited. |
URI: | http://hdl.handle.net/2433/191003 |
DOI(出版社版): | 10.1007/s11669-013-0224-3 |
出現コレクション: | 学術雑誌掲載論文等 |
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