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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| j.tet.2015.05.096.pdf | 250.54 kB | Adobe PDF | 見る/開く |
| タイトル: | Polymerization of vinyl ethers initiated by dendritic cations using flow microreactors |
| 著者: | Nagaki, Aiichiro Takumi, Masahiro Tani, Yosuke Yoshida, Jun-ichi |
| 著者名の別形: | 永木, 愛一郎 吉田, 潤一 |
| キーワード: | Microreactors Dendritic cation Polymerization Block copolymerization |
| 発行日: | Sep-2015 |
| 出版者: | Elsevier Ltd. |
| 誌名: | Tetrahedron |
| 巻: | 71 |
| 号: | 35 |
| 開始ページ: | 5973 |
| 終了ページ: | 5978 |
| 抄録: | Cationic polymerization of vinyl ethers initiated by an electrogenerated dendritic diarylcarbenium ion in the presence of 2, 6-di-tert-butylpyridine was developed using a flow microreactor. The carbocationic polymer end generated by polymerization of isobutyl vinyl ether was effectively trapped by various nucleophiles such as trimethyl(1-phenylvinyloxy)silane and allyltrimethylsilane to give polymers with very narrow molecular weight distribution. The block copolymerization of two vinyl ethers followed by trapping with nucleophiles was successfully accomplished to give structurally well-defined macromolecules. |
| 記述: | Available online 4 June 2015 |
| 著作権等: | © 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ The full-text file will be made open to the public on 4 June 2017 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/202006 |
| DOI(出版社版): | 10.1016/j.tet.2015.05.096 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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