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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| anie.201502951.pdf | 4.88 MB | Adobe PDF | 見る/開く |
| タイトル: | Tropolone as a High-Performance Robust Anchoring Group for Dye-Sensitized Solar Cells. |
| 著者: | Higashino, Tomohiro    https://orcid.org/0000-0002-9531-8569 (unconfirmed)Fujimori, Yamato Sugiura, Kenichi Tsuji, Yukihiro Ito, Seigo Imahori, Hiroshi |
| 著者名の別形: | 今堀, 博 |
| キーワード: | anchoring groups light harvesting porphyrinoids sensitizers solar cells |
| 発行日: | 27-Jul-2015 |
| 出版者: | wiley |
| 誌名: | Angewandte Chemie |
| 巻: | 54 |
| 号: | 31 |
| 開始ページ: | 9052 |
| 終了ページ: | 9056 |
| 抄録: | A tropolone group has been employed for the first time as an anchoring group for dye-sensitized solar cells (DSSCs). The DSSC based on a porphyrin, YD2-o-C8T, with a tropolone moiety exhibited a power-conversion efficiency of 7.7 %, which is only slightly lower than that observed for a reference porphyrin, YD2-o-C8, with a conventional carboxylic group. More importantly, YD2-o-C8T was found to be superior to YD2-o-C8 with respect to DSSC durability and binding ability to TiO2 . These results unambiguously demonstrate that tropolone is a highly promising dye-anchoring group for DSSCs in terms of device durability as well as photovoltaic performance. |
| 記述: | Article first published online: 16 JUN 2015 |
| 著作権等: | This is the peer reviewed version of the following article: Higashino, T., Fujimori, Y., Sugiura, K., Tsuji, Y., Ito, S. and Imahori, H. (2015), Tropolone as a High-Performance Robust Anchoring Group for Dye-Sensitized Solar Cells. Angew. Chem. Int. Ed., 54: 9052–9056, which has been published in final form at http://dx.doi.org/10.1002/anie.201502951. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. The full-text file will be made open to the public on 16 June 2016 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/202019 |
| DOI(出版社版): | 10.1002/anie.201502951 |
| PubMed ID: | 26080034 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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