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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| c5sc01266j.pdf | 390.16 kB | Adobe PDF | 見る/開く |
| タイトル: | Reaction of a diaryldigermyne with ethylene |
| 著者: | Sasamori, Takahiro Sugahara, Tomohiro Agou, Tomohiro Sugamata, Koh Guo, Jing Dong Nagase, Shigeru Tokitoh, Norihiro    https://orcid.org/0000-0003-1083-7245 (unconfirmed) |
| 著者名の別形: | 笹森, 貴裕 吾郷, 友宏 永瀬, 茂 時任, 宣博 |
| 発行日: | 24-Jun-2015 |
| 出版者: | Royal Society of Chemistry |
| 誌名: | Chemical Science |
| 巻: | 6 |
| 開始ページ: | 5526 |
| 終了ページ: | 5530 |
| 抄録: | Reaction of the stable digermyne BbtGeGeBbt (Bbt = 2, 6-[CH(SiMe<inf>3</inf>)<inf>2</inf>]<inf>2</inf>-4-[C(SiMe<inf>3</inf>)<inf>3</inf>]-C<inf>6</inf>H<inf>2</inf>) with ethylene initially afforded the corresponding 1, 2-digermacyclobutene. Depending on the reaction conditions applied, further reaction of this 1, 2-digermacyclobutene with ethylene furnished two different reaction products: a 1, 4-digermabicyclo[2.2.0]hexane or a bis(germiranyl)ethane. Combined experimental and theoretical results suggested that the 1, 4-digermabicyclo[2.2.0]hexane and the bis(germiranyl)ethane are the thermodynamic and kinetic reaction products, respectively. A reaction mechanism in agreement with these results was proposed. |
| 著作権等: | © The Royal Society of Chemistry 2015. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. |
| URI: | http://hdl.handle.net/2433/210578 |
| DOI(出版社版): | 10.1039/c5sc01266j |
| PubMed ID: | 28757948 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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