ダウンロード数: 577
このアイテムのファイル:
| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| acs.inorgchem.6b03028.pdf | 2.07 MB | Adobe PDF | 見る/開く |
| タイトル: | Magnetic–Nonmagnetic Phase Transition with Interlayer Charge Disproportionation of Nb3 Trimers in the Cluster Compound Nb3Cl8 |
| 著者: | Haraguchi, Yuya Michioka, Chishiro   Ishikawa, Manabu Nakano, Yoshiaki  https://orcid.org/0000-0003-3616-7286 (unconfirmed)Yamochi, Hideki Ueda, Hiroaki Yoshimura, Kazuyoshi |
| 著者名の別形: | 原口, 祐哉 道岡, 千城 石川, 学 中野, 義明 矢持, 秀起 植田, 浩明 吉村, 一良 |
| 発行日: | 10-Feb-2017 |
| 出版者: | American Chemical Society (ACS) |
| 誌名: | Inorganic Chemistry |
| 巻: | 56 |
| 号: | 6 |
| 開始ページ: | 3483 |
| 終了ページ: | 3488 |
| 抄録: | We grew large single crystals of the cluster magnet Nb3Cl8 with a magnetic triangular lattice and investigated its magnetic properties and crystal structure. In Nb3Cl8, the [Nb3]8+ cluster has a single unpaired spin, making it an S = 1/2 triangular lattice anti-ferromagnet. At low temperatures, Nb3Cl8 exhibits a magnetic–nonmagnetic phase transition driven by a charge disproportionation, in which the paramagnetic [Nb3]8+ clusters transform into alternating layers of nonmagnetic [Nb3]7+ and [Nb3]9+ clusters. The observed exotic phenomenon with the strong correlation between the magnetism and structure are based on the nature of the cluster magnetism. |
| 著作権等: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in 'Inorganic Chemistry', copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://doi.org/10.1021/acs.inorgchem.6b03028. The full-text file will be made open to the public on 10 February 2018 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
| URI: | http://hdl.handle.net/2433/219444 |
| DOI(出版社版): | 10.1021/acs.inorgchem.6b03028 |
| PubMed ID: | 28240540 |
| 出現コレクション: | 学術雑誌掲載論文等 |
このリポジトリに保管されているアイテムはすべて著作権により保護されています。