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タイトル: | Delocalization suppresses nonradiative charge recombination in polymer solar cells |
著者: | Natsuda, Shin-ichiro Saito, Toshiharu Shirouchi, Rei Imakita, Kenta Tamai, Yasunari |
著者名の別形: | 夏田, 慎一朗 齋藤, 俊晴 城内, 嶺 今北, 健太 玉井, 康成 |
キーワード: | Materials science Photochemistry |
発行日: | Nov-2022 |
出版者: | Springer Nature |
誌名: | Polymer Journal |
巻: | 54 |
号: | 11 |
開始ページ: | 1345 |
終了ページ: | 1353 |
抄録: | Suppressing nonradiative deactivation of charge transfer (CT) states is pivotal to realizing further improvements in the power conversion efficiencies of polymer solar cells (PSCs). According to the energy gap law, the nonradiative decay rate constant knr scales exponentially with decreasing CT state energy ECT; thereby, as long as knr is governed by the energy gap law, a decrease in ECT will inevitably increase nonradiative deactivation of CT states and hence decrease the power conversion efficiency. Here, we report the nonradiative decay dynamics of CT states generated in various nonfullerene-acceptor-based PSCs by using transient absorption spectroscopy. The absence of a strong correlation between knr and ECT indicates that the energy gap law is not valid for these PSCs and that parameters other than ECT contribute significantly to knr. We found that knr decreased with an increase in materials’ crystallinities, indicating that increasing crystallinity leads to CT state delocalization, which in turn mitigates the nonradiative deactivation of CT states. |
著作権等: | This version of the article has been accepted for publication, after peer review (when applicable) and is subject to Springer Nature’s AM terms of use, but is not the Version of Record and does not reflect post-acceptance improvements, or any corrections. The Version of Record is available online at: http://dx.doi.org/10.1038/s41428-022-00685-1 The full-text file will be made open to the public on 25 January 2023 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
URI: | http://hdl.handle.net/2433/276638 |
DOI(出版社版): | 10.1038/s41428-022-00685-1 |
出現コレクション: | 学術雑誌掲載論文等 |
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