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DCフィールド | 値 | 言語 |
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dc.contributor.author | Yasui, Yoshizumi | en |
dc.contributor.author | Kamisaki, Haruhi | en |
dc.contributor.author | Ishida, Takayuki | en |
dc.contributor.author | Takemoto, Yoshiji | en |
dc.contributor.alternative | 竹本, 佳司 | ja |
dc.date.accessioned | 2010-03-04T06:16:49Z | - |
dc.date.available | 2010-03-04T06:16:49Z | - |
dc.date.issued | 2010-03-13 | - |
dc.identifier.issn | 00404020 | - |
dc.identifier.uri | http://hdl.handle.net/2433/101563 | - |
dc.description.abstract | The cyanoamidation of olefins was achieved. When N-(2-vinylphenyl)cyanoformamides were treated with palladium catalyst, intramolecular cyanoamidation took place to give corresponding 3, 3-disubstituted oxindoles. P(t-Bu)3 showed a remarkable effect on this reaction. When it was used with Pd(dba)2, the reaction was completed in 15 min at 100 oC for many substrates. Furthermore, the enantioselective cyanoamidation was accomplished with Pd(dba)2 and an optically active phosphoramidite to provide optically active 3, 3-disubstituted oxindoles. Manipulation of the resulting oxindoles has been studied. | en |
dc.language.iso | eng | - |
dc.publisher | Elsevier | en |
dc.rights | c 2010 Elsevier Ltd. All rights reserved. | en |
dc.rights | この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | ja |
dc.rights | This is not the published version. Please cite only the published version. | en |
dc.title | Synthesis of 3,3-disubstituted oxindoles through Pd-catalyzed intramolecular cyanoamidation | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.jtitle | Tetrahedron | en |
dc.identifier.volume | 66 | - |
dc.identifier.issue | 11 | - |
dc.identifier.spage | 1980 | - |
dc.identifier.epage | 1989 | - |
dc.relation.doi | 10.1016/j.tet.2010.01.073 | - |
dc.textversion | author | - |
dcterms.accessRights | open access | - |
出現コレクション: | 学術雑誌掲載論文等 |
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