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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| PAC-CON-08-08-01.pdf | 214.11 kB | Adobe PDF | 見る/開く |
| タイトル: | Chiral pi-conjugated organoboron polymers |
| 著者: | Matsumoto, Fukashi Chujo, Yoshiki |
| キーワード: | conjugated polymers organoboron polymers chiral group chiroptical property hydroboration polymerization |
| 発行日: | Mar-2009 |
| 出版者: | International Union of Pure and Applied Chemistry |
| 誌名: | PURE AND APPLIED CHEMISTRY |
| 巻: | 81 |
| 号: | 3 |
| 開始ページ: | 433 |
| 終了ページ: | 437 |
| 抄録: | A novel π-conjugated organoboron polymer with a chiral side chain was prepared by way of hydroboration polymerization between an optically active diyne monomer and triisopropylphenylborane. The achiral analog of this organoboron polymer was also prepared as reference material. Optical properties and optical activity were investigated by UV-vis absorption, fluorescence emission, and circular dichroism (CD) spectroscopy. Concentration dependence and the influence of solvent effects upon chiroptical activity are described. |
| 著作権等: | Copyright © 2009 International Union of Pure and Applied Chemistry |
| URI: | http://hdl.handle.net/2433/109940 |
| DOI(出版社版): | 10.1351/PAC-CON-08-08-01 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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