<研究ノート>機能性π共役系分子の直接的多重アリール化

Abstract

Peripheral arylation of functional aromatic nuclei can customize the electronic and steric natures of the parent nuclei through extension of π-conjugation, thereby being useful in pursuing new advanced materials. We disclose that state-of-the-art palladium-catalyzed direct arylation is applicable to modification of functional aromatics such as tetrathiafulvalene and porphyrins as a much more efficient method than the well-known cross-coupling strategy.