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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| s10570-012-9772-7.pdf | 556.48 kB | Adobe PDF | 見る/開く |
| タイトル: | Synthesis of (zinc(II) phthalocyanine)-containing cellulose derivative using phthalocyanine-ring formation reaction |
| 著者: | Saito, Yasuko Takano, Toshiyuki   Sakakibara, Keita  https://orcid.org/0000-0002-6013-695X (unconfirmed)Kamitakahara, Hiroshi https://orcid.org/0000-0002-0130-1919 (unconfirmed)Nakatsubo, Fumiaki |
| 著者名の別形: | 斉藤, 靖子 |
| キーワード: | Cellulose Phthalocyanine Phthalocyaninato zinc(II) Regioselective Langmuir–Blodgett film Photocurrent generation system |
| 発行日: | Dec-2012 |
| 出版者: | Springer Netherlands |
| 誌名: | Cellulose |
| 巻: | 19 |
| 号: | 6 |
| 開始ページ: | 2105 |
| 終了ページ: | 2114 |
| 抄録: | 2, 3-Di-O-myristyl-6-O-(zinc(II) phthalocyaninyl) cellulose (5) was synthesized from cellulose (1) by five reaction steps via 6-O-(3′, 4′-dicyanophenyl)-2, 3-di-O-myristyl cellulose (4). The key reaction was phthalocyanine-ring formation on a cellulose backbone, that is, the reaction of compound 4 with o-phthalodinitrile in the presence of hexamethyldisilazane and zinc acetate in DMF afforded to compound 5 in 35.4 % yield. Consequently, the degree of substitution with phthalocyanine moieties of compound 5 was 0.38. The LB monolayer film of compound 5 on an indium tin oxide (ITO) electrode was found to show photocurrent generation performance at 680 nm. |
| 著作権等: | The final publication is available at www.springerlink.com この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
| URI: | http://hdl.handle.net/2433/162283 |
| DOI(出版社版): | 10.1007/s10570-012-9772-7 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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