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ファイル | 記述 | サイズ | フォーマット | |
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molecules171112792.pdf | 347.46 kB | Adobe PDF | 見る/開く |
タイトル: | DNA as a chiral scaffold for asymmetric synthesis. |
著者: | Park, Soyoung Sugiyama, Hiroshi https://orcid.org/0000-0001-8923-5946 (unconfirmed) |
著者名の別形: | 朴, 昭映 杉山, 弘 |
キーワード: | DNA asymmetric synthesis helical chirality hybrid catalyst |
発行日: | 31-Oct-2012 |
出版者: | MDPI |
誌名: | Molecules |
巻: | 17 |
号: | 11 |
開始ページ: | 12792 |
終了ページ: | 12803 |
抄録: | The application of DNA-based hybrid catalysts for enantioselective synthesis has recently emerged. These catalysts, self-assembled from DNA and a metal complex with a specific ligand through supramolecular or covalent anchoring strategies, have demonstrated high enantioselectivity in a variety of carbon-carbon or carbon-heteroatom bond-forming reactions and have expanded their role in asymmetric catalysis. In this review, we summarize the advent and significant progress of DNA-based asymmetric catalysis and discuss remaining challenges in using DNA as a chiral scaffold. We hope that this review will inspire many of today’s active scientists in asymmetric catalysis. |
著作権等: | © 2012 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/). |
URI: | http://hdl.handle.net/2433/166079 |
DOI(出版社版): | 10.3390/molecules171112792 |
PubMed ID: | 23114615 |
出現コレクション: | 学術雑誌掲載論文等 |
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