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タイトル: | Systematic mechanochemical preparation of a series of coordination pillared layer frameworks. |
著者: | Sakamoto, Hirotoshi https://orcid.org/0000-0002-0873-1321 (unconfirmed) Matsuda, Ryotaro Kitagawa, Susumu https://orcid.org/0000-0001-6956-9543 (unconfirmed) |
著者名の別形: | 坂本, 裕俊 北川, 進 |
発行日: | 20-Jan-2012 |
出版者: | Royal Society of Chemistry |
誌名: | Dalton transactions |
巻: | 41 |
号: | 14 |
開始ページ: | 3956 |
終了ページ: | 3961 |
抄録: | A detailed investigation into the mechanochemical synthesis of coordination pillared-layer frameworks (CPLs), particularly CPL-1, was carried out. In the case of CPL-1, a two-step reaction was observed (from the starting reactants to the final product). In the conventional solution process, no intermediate state was detected. We found that moisture is essential in both the reaction steps. After the final product was washed, it showed the same sorption ability as the product prepared from a solution process. We further demonstrated the systematic preparation of other CPLs (CPL-2, 3, 4, 5, and 15) by the mechanochemical method under humid conditions, even though some of the ligands are almost insoluble in water. Our findings indicate that mechanochemical synthesis is a promising alternative method for the systematic and large-scale production of PCPs. Its advantages include the following: reduced pollution, low cost, simplicity of the process, ease of handling, efficient reaction rate, selectivity, and the issue of low solubility of reactants is overcome. |
著作権等: | © The Royal Society of Chemistry 2012 この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
URI: | http://hdl.handle.net/2433/166081 |
DOI(出版社版): | 10.1039/c2dt12012g |
PubMed ID: | 22261929 |
出現コレクション: | 学術雑誌掲載論文等 |
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