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DCフィールド | 値 | 言語 |
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dc.contributor.author | Herrera, Marvin Ustaris | en |
dc.contributor.author | Ichii, Takashi | en |
dc.contributor.author | Murase, Kuniaki | en |
dc.contributor.author | Sugimura, Hiroyuki | en |
dc.contributor.alternative | 杉村, 博之 | ja |
dc.date.accessioned | 2013-11-01T01:11:47Z | - |
dc.date.available | 2013-11-01T01:11:47Z | - |
dc.date.issued | 2013-12-01 | - |
dc.identifier.issn | 0021-9797 | - |
dc.identifier.uri | http://hdl.handle.net/2433/179382 | - |
dc.description.abstract | The photochemical grafting of methyl groups onto an n-type Si(111) substrate was successfully achieved using a Grignard reagent. The preparation involved illuminating a hydrogen-terminated Si(111) that was immersed in a CH3MgBr-THF solution. The success was attributed to the ability of the n-type hydrogenated substrate to produce holes on its surface when illuminated. The rate of grafting methyl groups onto the silicon surface was higher when a larger illumination intensity or when a substrate with lower dopant concentration was used. In addition, the methylated layer has an atomically flat structure, has a hydrophobic surface, and has electron affinity that was lower than the bulk Si. | en |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier Inc. | en |
dc.rights | © 2013 Elsevier Inc. | en |
dc.rights | この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | ja |
dc.rights | This is not the published version. Please cite only the published version. | en |
dc.subject | Methyl-terminated Si | en |
dc.subject | Photochemical grafting | en |
dc.subject | Grignard reagent | en |
dc.subject | Self-assembled monolayer | en |
dc.title | Photochemical grafting of methyl groups on a Si(111) surface using a Grignard reagent. | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.ncid | AA00695804 | - |
dc.identifier.jtitle | Journal of colloid and interface science | en |
dc.identifier.volume | 411 | - |
dc.identifier.spage | 145 | - |
dc.identifier.epage | 151 | - |
dc.relation.doi | 10.1016/j.jcis.2013.08.035 | - |
dc.textversion | author | - |
dc.identifier.pmid | 24041547 | - |
dcterms.accessRights | open access | - |
出現コレクション: | 学術雑誌掲載論文等 |
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