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dc.contributor.author | Nakaya, K. | en |
dc.contributor.author | Nakata, A. | en |
dc.contributor.author | Hirai, T. | en |
dc.contributor.author | Ogumi, Z. | en |
dc.contributor.alternative | 平井, 敏郎 | ja |
dc.date.accessioned | 2015-04-03T07:05:51Z | - |
dc.date.available | 2015-04-03T07:05:51Z | - |
dc.date.issued | 2014-11-13 | - |
dc.identifier.issn | 0013-4651 | - |
dc.identifier.uri | http://hdl.handle.net/2433/196780 | - |
dc.description.abstract | We have studied in detail the electrochemical reaction of nickel in several kinds of molar ratio-controlled molten salts consisting of AlCl(3) and 1-butylpyridinium chloride (BPC) at 40°C. We observed NiCl(2) as an oxidation product from nickel on the surface of the electrode in slightly acidic AlCl(3)/BPC salts with molar ratios of 1.05/1.0 and 1.1/1.0. However, in strongly acidic salt with the ratio of 1.5/1.0, NiCl(2) deposits on the electrode less than when in the above salts, and no NiCl(29) is observed in basic and neutral salts with the ratio of 1.0/1.0 or less AlCl(3) content. This suggests that [NiCl(4)](2−) ions form as the oxidation of nickel in such neutral and basic AlC(3)/BPC (salts). | en |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Electrochemical Society | en |
dc.rights | © The Author(s) 2014. Published by ECS. | en |
dc.rights | This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited. | en |
dc.title | Oxidation of Nickel in AlCl3-1-Butylpyridinium Chloride at Ambient Temperature | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.ncid | AA00697016 | - |
dc.identifier.jtitle | Journal of the Electrochemical Society | en |
dc.identifier.volume | 162 | - |
dc.identifier.issue | 1 | - |
dc.identifier.spage | D42 | - |
dc.identifier.epage | D48 | - |
dc.relation.doi | 10.1149/2.0401501jes | - |
dc.textversion | publisher | - |
dcterms.accessRights | open access | - |
出現コレクション: | 学術雑誌掲載論文等 |
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