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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| anie.201308551.pdf | 298.71 kB | Adobe PDF | 見る/開く |
| タイトル: | Synthesis and catalytic activities of porphyrin-based PCP pincer complexes. |
| 著者: | Fujimoto, Keisuke Yoneda, Tomoki Yorimitsu, Hideki    https://orcid.org/0000-0002-0153-1888 (unconfirmed)Osuka, Atsuhiro |
| 著者名の別形: | 依光, 英樹 |
| キーワード: | ligand design metalation porphyrinoid reaction mechanisms transition metals |
| 発行日: | 11-Dec-2013 |
| 出版者: | wiley |
| 誌名: | Angewandte Chemie - International Edition |
| 巻: | 53 |
| 号: | 4 |
| 開始ページ: | 1127 |
| 終了ページ: | 1130 |
| 抄録: | 2, 18-Bis(diphenylphosphino)porphyrins undergo peripheral cyclometalation with group 10 transition-metal salts to afford the corresponding porphyrin-based PCP pincer complexes. The porphyrinic plane and the PCP-pincer unit are apparently coplanar, with small strain. The catalytic activities of the porphyrin-based pincer complexes at the periphery were investigated in the allylation of benzaldehyde with allylstannane and in the 1, 4-reduction of chalcone to discover the electronic interplay between the inner metal and the outer metal in catalysis. |
| 著作権等: | This is the peer reviewed version of the following article: Fujimoto, K., Yoneda, T., Yorimitsu, H. and Osuka, A. (2014), Synthesis and Catalytic Activities of Porphyrin-Based PCP Pincer Complexes. Angew. Chem. Int. Ed., 53: 1127–1130, which has been published in final form at http://dx.doi.org/10.1002/anie.201308551. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/198445 |
| DOI(出版社版): | 10.1002/anie.201308551 |
| PubMed ID: | 24339372 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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