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Title: Catalytic asymmetric synthesis of the pentacyclic core of (-)-nakadomarin A via oxazolidine as an iminium cation equivalent.
Authors: Tsuji, Nobuya
Stadler, Michael
Kazumi, Naoya
Inokuma, Tsubasa
Kobayashi, Yusuke  kyouindb  KAKEN_id
Takemoto, Yoshiji  kyouindb  KAKEN_id
Author's alias: 小林, 祐輔
竹本, 佳司
Issue Date: 27-Aug-2014
Publisher: Royal Society of Chemistry
Journal title: Organic & biomolecular chemistry
Volume: 12
Issue: 40
Start page: 7919
End page: 7922
Abstract: A facile and catalytic asymmetric synthesis of the pentacyclic core of (-)-nakadomarin A, containing all the stereogenic centers of the natural product was achieved. The key intermediate involves the oxazolidine moiety as an iminium cation equivalent. An efficient method for the removal of the N-hydroxyethyl group is also described.
Rights: This journal is © The Royal Society of Chemistry 2014.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
DOI(Published Version): 10.1039/c4ob01678e
PubMed ID: 25216237
Appears in Collections:Journal Articles

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