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dc.contributor.authorTanaka, Kazuoen
dc.contributor.authorHirose, Amaneen
dc.contributor.authorTamashima, Kenjien
dc.contributor.authorChujo, Yoshikien
dc.contributor.alternative田中, 一生ja
dc.contributor.alternative中條, 善樹ja
dc.date.accessioned2015-10-27T01:19:37Z-
dc.date.available2015-10-27T01:19:37Z-
dc.date.issued2015-03-03-
dc.identifier.issn1022-1336-
dc.identifier.urihttp://hdl.handle.net/2433/200781-
dc.description.abstractThe synthesis of a platinum diketonate-based alternating copolymer containing a fluorene unit and its oxygen-resistant phosphorescence are reported. The polymerization is executed via palladium-catalyzed Suzuki-Miyaura coupling reaction. The synthesized polymer shows good solubility in common organic solvents and processability to form homogeneous films. By optical measurements it is found that the synthesized polymer shows phosphorescence from a triplet π-π* ligand-centered transition, and interestingly, the emission is hardly influenced by oxygen. Phosphorescence is observed from both solution and film samples under aerobic conditions. The new idea of obtaining emissive materials based on conjugated polymers showing oxygen-resistant phosphorescence is presented here.en
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherwileyen
dc.rightsThis is the peer reviewed version of the following article: Tanaka, K., Hirose, A., Tamashima, K. and Chujo, Y. (2015), Synthesis of a Platinum Diketonate-Containing Polymer Showing Oxygen-Resistant Phosphorescence. Macromol. Rapid Commun., 36: 684–688, which has been published in final form at http://dx.doi.org/10.1002/marc.201500104. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.en
dc.rightsThe full-text file will be made open to the public on 3 MAR 2016 in accordance with publisher's 'Terms and Conditions for Self-Archiving'en
dc.rightsこの論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。ja
dc.rightsThis is not the published version. Please cite only the published version.en
dc.subjectplatinum complexesen
dc.subjectdiketonateen
dc.subjectoxygenen
dc.subjectconjugated polymersen
dc.titleSynthesis of a platinum diketonate-containing polymer showing oxygen-resistant phosphorescence.en
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.ncidAA10984320-
dc.identifier.jtitleMacromolecular rapid communicationsen
dc.identifier.volume36-
dc.identifier.issue7-
dc.identifier.spage684-
dc.identifier.epage688-
dc.relation.doi10.1002/marc.201500104-
dc.textversionauthor-
dc.startdate.bitstreamsavailable2016-03-03-
dc.identifier.pmid25737390-
dcterms.accessRightsopen access-
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