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j.jmr.2015.06.003.pdf1.53 MBAdobe PDF見る/開く
タイトル: Susceptibility cancellation of a microcoil wound with a paramagnetic-liquid-filled copper capillary.
著者: Takeda, Kazuyuki  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0002-6743-0932 (unconfirmed)
Takasaki, Tomoya
Takegoshi, K  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0002-4613-2987 (unconfirmed)
著者名の別形: 武田, 和行
キーワード: Microcoil
Bulk magnetic susceptibility
Copper capillary
Paramagnetic liquid
Susceptibility cancellation
発行日: Sep-2015
出版者: Elsevier Inc.
誌名: Journal of magnetic resonance
巻: 258
開始ページ: 1
終了ページ: 5
抄録: Even though microcoils improve the sensitivity of NMR measurement of tiny samples, magnetic-field inhomogeneity due to the bulk susceptibility effect of the coil material can cause serious resonance-line broadening. Here, we propose to fabricate the microcoil using a thin, hollow copper capillary instead of a wire and fill paramagnetic liquid inside the capillary, so as to cancel the diamagnetic contribution of the copper. Susceptibility cancellation is demonstrated using aqueous solution of NiSO4. In addition, the paramagnetic liquid serves as coolant when it is circulated through the copper capillary, effectively transferring the heat generated by radiofrequency pulses.
著作権等: © 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
The full-text file will be made open to the public on 30 September 2017 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.
This is not the published version. Please cite only the published version.
この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
URI: http://hdl.handle.net/2433/201600
DOI(出版社版): 10.1016/j.jmr.2015.06.003
PubMed ID: 26150376
出現コレクション:学術雑誌掲載論文等

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