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タイトル: | Tin-Doped Inorganic Amorphous Films for Use as Transparent Monolithic Phosphors. |
著者: | Masai, Hirokazu ![]() Miyata, Hiroki Yamada, Yasuhiro Okumura, Shun Yanagida, Takayuki Kanemitsu, Yoshihiko ![]() ![]() ![]() |
著者名の別形: | 正井, 博和 |
発行日: | 10-Jun-2015 |
出版者: | Nature Publishing Group |
誌名: | Scientific reports |
巻: | 5 |
論文番号: | 11224 |
抄録: | Although inorganic crystalline phosphors can exhibit high quantum efficiency, their use in phosphor films has been limited by a reliance on organic binders that have poor durability when exposed to high-power and/or high excitation energy light sources. To address this problem, Sn(2+)-doped transparent phosphate films measuring several micrometers in thickness have been successfully prepared through heat treatment and a subsequent single dip-coating process. The resulting monolithic inorganic amorphous film exhibited an internal quantum efficiency of over 60% and can potentially utilize transmitted light. Analysis of the film's emissivity revealed that its color can be tuned by changing the amount of Mn and Sn added to influence the energy transfer from Sn(2+) to Mn(2+). It is therefore concluded that amorphous films containing such emission centers can provide a novel and viable alternative to conventional amorphous films containing crystalline phosphors in light-emitting devices. |
著作権等: | This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ |
URI: | http://hdl.handle.net/2433/201625 |
DOI(出版社版): | 10.1038/srep11224 |
PubMed ID: | 26061744 |
出現コレクション: | 学術雑誌掲載論文等 |
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