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dc.contributor.author | Kitada, Atsushi | en |
dc.contributor.author | Kang, Yuu | en |
dc.contributor.author | Matsumoto, Kazuhiko | en |
dc.contributor.author | Fukami, Kazuhiro | en |
dc.contributor.author | Hagiwara, Rika | en |
dc.contributor.author | Murase, Kuniaki | en |
dc.contributor.alternative | 邑瀬, 邦明 | ja |
dc.date.accessioned | 2015-11-20T07:29:56Z | - |
dc.date.available | 2015-11-20T07:29:56Z | - |
dc.date.issued | 2015-05-02 | - |
dc.identifier.issn | 0013-4651 | - |
dc.identifier.uri | http://hdl.handle.net/2433/201844 | - |
dc.description.abstract | We prepared less volatile and halide-free electrolytes for room temperature non-dendritic magnesium (Mg) electrodeposition by mixing a Mg[2+]-amide-containing ionic liquid (IL) with equimolar glyme (Mg[2+]+IL : glyme = 1:1). Raman spectroscopy suggested that in the equimolar mixture most glyme molecules are coordinated to Mg[2+] cations and/or IL cations, which is also supported by a single crystal X-ray diffraction study. The glyme-coordinated IL electrolytes showed sizable redox currents (order of mA cm–2), while aging deterioration of electrochemical properties was observed for the triglyme mixture due to partial bath decomposition. The tetraglyme-coordinated IL electrolyte enabled flat electrodeposition of Mg with a metallic luster and showed with very high anodic stability (ca. +4 V vs. Mg) because of decrease in uncoordinated glymes, which can be used for high-voltage Mg ion batteries. | en |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Electrochemical Society | en |
dc.rights | This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited. | en |
dc.subject | coordination | en |
dc.subject | electrodeposition | en |
dc.subject | glyme | en |
dc.subject | ionic liquid | en |
dc.subject | magnesium | en |
dc.subject | raman | en |
dc.subject | room temperature | en |
dc.subject | single crystal | en |
dc.title | Room Temperature Magnesium Electrodeposition from Glyme-Coordinated Ammonium Amide Electrolytes | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.ncid | AA00697016 | - |
dc.identifier.jtitle | Journal of the Electrochemical Society | en |
dc.identifier.volume | 162 | - |
dc.identifier.issue | 8 | - |
dc.identifier.spage | D389 | - |
dc.identifier.epage | D396 | - |
dc.relation.doi | 10.1149/2.0731508jes | - |
dc.textversion | publisher | - |
dcterms.accessRights | open access | - |
出現コレクション: | 学術雑誌掲載論文等 |
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