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dc.contributor.authorHigashino, Tomohiroen
dc.contributor.authorImahori, Hiroshien
dc.contributor.alternative今堀, 博ja
dc.date.accessioned2015-11-24T02:36:52Z-
dc.date.available2015-11-24T02:36:52Z-
dc.date.issued2015-08-04-
dc.identifier.issn0947-6539-
dc.identifier.urihttp://hdl.handle.net/2433/201853-
dc.description.abstractBispyrroloheteroles have been synthesized to address their intrinsic structural, optical, and electrochemical properties. The X-ray crystal structures and calculated natural bond orbital (NBO) bond orders unambiguously demonstrated the existence of a two pyrrole-fused five-membered ring with short exocyclic C-C double bonds and long endocyclic C-C single bonds, supporting that the bispyrroloheteroles are rare examples of structurally characterized hybrid [5]radialenes. The bispyrroloheteroles were found to act as an electron-donating unit, which would be fascinating for the rational design of new charge-transporting and donor-acceptor photovoltaic materials as well as versatile charge-transfer complexes.en
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherwileyen
dc.rightsThis is the peer reviewed version of the following article: Higashino, T. and Imahori, H. (2015), Hybrid [5]Radialenes with Bispyrroloheteroles: New Electron-Donating Units. Chem. Eur. J., 21: 13375–13381, which has been published in final form at http://dx.doi.org/10.1002/chem.201501822. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.en
dc.rightsThe full-text file will be made open to the public on 4 August 2016in accordance with publisher's 'Terms and Conditions for Self-Archiving'.en
dc.rightsこの論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。ja
dc.rightsThis is not the published version. Please cite only the published version.en
dc.subjectcharge transferen
dc.subjectdonor–acceptor systemsen
dc.subjectheterocyclesen
dc.subjectUV/Vis spectroscopyen
dc.subjectX-ray diffractionen
dc.titleHybrid [5]Radialenes with Bispyrroloheteroles: New Electron-Donating Units.en
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.ncidAA11076269-
dc.identifier.jtitleChemistry - A European Journalen
dc.identifier.volume21-
dc.identifier.issue38-
dc.identifier.spage13375-
dc.identifier.epage13381-
dc.relation.doi10.1002/chem.201501822-
dc.textversionauthor-
dc.startdate.bitstreamsavailable2016-08-04-
dc.identifier.pmid26242481-
dcterms.accessRightsopen access-
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