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chem.201501822.pdf | 5.08 MB | Adobe PDF | 見る/開く |
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DCフィールド | 値 | 言語 |
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dc.contributor.author | Higashino, Tomohiro | en |
dc.contributor.author | Imahori, Hiroshi | en |
dc.contributor.alternative | 今堀, 博 | ja |
dc.date.accessioned | 2015-11-24T02:36:52Z | - |
dc.date.available | 2015-11-24T02:36:52Z | - |
dc.date.issued | 2015-08-04 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.uri | http://hdl.handle.net/2433/201853 | - |
dc.description.abstract | Bispyrroloheteroles have been synthesized to address their intrinsic structural, optical, and electrochemical properties. The X-ray crystal structures and calculated natural bond orbital (NBO) bond orders unambiguously demonstrated the existence of a two pyrrole-fused five-membered ring with short exocyclic C-C double bonds and long endocyclic C-C single bonds, supporting that the bispyrroloheteroles are rare examples of structurally characterized hybrid [5]radialenes. The bispyrroloheteroles were found to act as an electron-donating unit, which would be fascinating for the rational design of new charge-transporting and donor-acceptor photovoltaic materials as well as versatile charge-transfer complexes. | en |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | wiley | en |
dc.rights | This is the peer reviewed version of the following article: Higashino, T. and Imahori, H. (2015), Hybrid [5]Radialenes with Bispyrroloheteroles: New Electron-Donating Units. Chem. Eur. J., 21: 13375–13381, which has been published in final form at http://dx.doi.org/10.1002/chem.201501822. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | en |
dc.rights | The full-text file will be made open to the public on 4 August 2016in accordance with publisher's 'Terms and Conditions for Self-Archiving'. | en |
dc.rights | この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | ja |
dc.rights | This is not the published version. Please cite only the published version. | en |
dc.subject | charge transfer | en |
dc.subject | donor–acceptor systems | en |
dc.subject | heterocycles | en |
dc.subject | UV/Vis spectroscopy | en |
dc.subject | X-ray diffraction | en |
dc.title | Hybrid [5]Radialenes with Bispyrroloheteroles: New Electron-Donating Units. | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.ncid | AA11076269 | - |
dc.identifier.jtitle | Chemistry - A European Journal | en |
dc.identifier.volume | 21 | - |
dc.identifier.issue | 38 | - |
dc.identifier.spage | 13375 | - |
dc.identifier.epage | 13381 | - |
dc.relation.doi | 10.1002/chem.201501822 | - |
dc.textversion | author | - |
dc.startdate.bitstreamsavailable | 2016-08-04 | - |
dc.identifier.pmid | 26242481 | - |
dcterms.accessRights | open access | - |
出現コレクション: | 学術雑誌掲載論文等 |

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