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Title: Formation of Foam-like Microstructural Carbon Material by Carbonization of Porous Coordination Polymers through a Ligand-Assisted Foaming Process.
Authors: Kongpatpanich, Kanokwan
Horike, Satoshi  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0001-8530-6364 (unconfirmed)
Fujiwara, Yu-Ichi
Ogiwara, Naoki
Nishihara, Hirotomo
Kitagawa, Susumu  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0001-6956-9543 (unconfirmed)
Author's alias: 堀毛, 悟史
北川, 進
Keywords: porous carbon
foams
porous coordination polymer
Issue Date: 3-Aug-2015
Publisher: wiley
Journal title: Chemistry - A European Journal
Volume: 21
Issue: 38
Start page: 13278
End page: 13283
Abstract: Porous carbon material with a foam-like microstructure has been synthesized by direct carbonization of porous coordination polymer (PCP). In situ generation of foaming agents by chemical reactions of ligands in PCP during carbonization provides a simple way to create lightweight carbon material with a foam-like microstructure. Among several substituents investigated, the nitro group has been shown to be the key to obtain the unique foam-like microstructure, which is due to the fast kinetics of gas evolution during carbonization. Foam-like microstructural carbon materials showed higher pore volume and specific capacitance compared to a microporous carbon.
Rights: This is the peer reviewed version of the following article: Kongpatpanich, K., Horike, S., Fujiwara, Y.-i., Ogiwara, N., Nishihara, H. and Kitagawa, S. (2015), Formation of Foam-like Microstructural Carbon Material by Carbonization of Porous Coordination Polymers through a Ligand-Assisted Foaming Process. Chem. Eur. J., 21: 13278–13283, which has been published in final form at http://dx.doi.org/10.1002/chem.201501988. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
The full-text file will be made open to the public on 3 August 2016 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.
This is not the published version. Please cite only the published version.
この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
URI: http://hdl.handle.net/2433/201894
DOI(Published Version): 10.1002/chem.201501988
PubMed ID: 26242622
Appears in Collections:Journal Articles

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