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DCフィールド | 値 | 言語 |
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dc.contributor.author | Iwata, Akira | en |
dc.contributor.author | Inuki, Shinsuke | en |
dc.contributor.author | Oishi, Shinya | en |
dc.contributor.author | Fujii, Nobutaka | en |
dc.contributor.author | Ohno, Hiroaki | en |
dc.contributor.alternative | 藤井, 信孝 | ja |
dc.contributor.alternative | 大野, 浩章 | ja |
dc.date.accessioned | 2015-12-02T02:41:37Z | - |
dc.date.available | 2015-12-02T02:41:37Z | - |
dc.date.issued | 2015-09 | - |
dc.identifier.issn | 0040-4020 | - |
dc.identifier.uri | http://hdl.handle.net/2433/202050 | - |
dc.description | Available online 9 May 2015 | en |
dc.description.abstract | Herein, we report the palladium-catalyzed cyclization reactions of indoles bearing a propargyl chloride side chain at their 3-position. In the presence of an external nucleophile, such as a sulfonamide or malonate, indoles bearing a propargyl group at their 3-position gave fused tetracyclic spiroindolines preferentially. However, in the absence of an external nucleophile, the same substrates afforded spiroindoles. Our attempts to develop a catalytic asymmetric spirocyclization onto a propargylpalladium species are also presented in this paper. | en |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier Ltd. | en |
dc.rights | © 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ | en |
dc.rights | The full-text file will be made open to the public on 9 May 2017 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. | en |
dc.rights | This is not the published version. Please cite only the published version. | en |
dc.rights | この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | ja |
dc.subject | Palladium | en |
dc.subject | Spiroindole | en |
dc.subject | Cascade cyclization | en |
dc.subject | Catalytic asymmetric reaction | en |
dc.title | Convenient synthesis of spiroindole derivatives via palladium-catalyzed cyclization of propargyl chlorides | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.ncid | AA00861787 | - |
dc.identifier.jtitle | Tetrahedron | en |
dc.identifier.volume | 71 | - |
dc.identifier.issue | 37 | - |
dc.identifier.spage | 6580 | - |
dc.identifier.epage | 6585 | - |
dc.relation.doi | 10.1016/j.tet.2015.05.006 | - |
dc.textversion | author | - |
dc.startdate.bitstreamsavailable | 2017-05-09 | - |
dcterms.accessRights | open access | - |
出現コレクション: | 学術雑誌掲載論文等 |
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