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dc.contributor.author | Fujii, Shintaro | en |
dc.contributor.author | Nakano, Mayu | en |
dc.contributor.author | Yamaoka, Yousuke | en |
dc.contributor.author | Takasu, Kiyosei | en |
dc.contributor.author | Yamada, Ken-ichi | en |
dc.contributor.author | Tomioka, Kiyoshi | en |
dc.contributor.alternative | 山田, 健一 | ja |
dc.date.accessioned | 2015-12-07T07:44:09Z | - |
dc.date.available | 2015-12-07T07:44:09Z | - |
dc.date.issued | 2015-06 | - |
dc.identifier.issn | 0040-4039 | - |
dc.identifier.uri | http://hdl.handle.net/2433/202095 | - |
dc.description | Available online 27 November 2014 | en |
dc.description.abstract | A reaction of N-tosyl cycloalkanecarbaldimines with iodomethyl pivalate was initiated by triethylborane to give pivaloyloxymethylated products bearing 3-iodocycloalkyl groups. Radical addition of pivaloyloxymethyl to imines generates aminyl radicals, which then regioselectively cleave Csingle bondH bonds at the 3-position of the cycloalkane moieties. The resulting carbon-centered radicals are trapped with iodine. DFT calculations rationalized stereo- and regioselectivity. | en |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier Ltd. | en |
dc.rights | © 2014. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ | en |
dc.rights | The full-text file will be made open to the public on 27 November 2016 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. | en |
dc.rights | この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | ja |
dc.rights | This is not the published version. Please cite only the published version. | en |
dc.subject | Radical reactions | en |
dc.subject | Cascade reactions | en |
dc.subject | Csingle bondH functionalization | en |
dc.subject | Aminyl radical generation | en |
dc.subject | Csingle bondC bond formation | en |
dc.title | Contiguous radical pivaloyloxymethylation–directed C(sp3)–H iodination of N-tosyl cycloalkanecarbaldimine | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.ncid | AA00861801 | - |
dc.identifier.jtitle | Tetrahedron Letters | en |
dc.identifier.volume | 56 | - |
dc.identifier.issue | 23 | - |
dc.identifier.spage | 3086 | - |
dc.identifier.epage | 3089 | - |
dc.relation.doi | 10.1016/j.tetlet.2014.11.105 | - |
dc.textversion | author | - |
dc.startdate.bitstreamsavailable | 2016-11-27 | - |
dcterms.accessRights | open access | - |
出現コレクション: | 学術雑誌掲載論文等 |
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