ダウンロード数: 541
このアイテムのファイル:
ファイル | 記述 | サイズ | フォーマット | |
---|---|---|---|---|
anie.201500700.pdf | 419.58 kB | Adobe PDF | 見る/開く |
タイトル: | Total Synthesis of Ellagitannins through Regioselective Sequential Functionalization of Unprotected Glucose. |
著者: | Takeuchi, Hironori Mishiro, Kenji Ueda, Yoshihiro https://orcid.org/0000-0002-5485-2722 (unconfirmed) Fujimori, Yusuke Furuta, Takumi Kawabata, Takeo https://orcid.org/0000-0002-9959-0420 (unconfirmed) |
著者名の別形: | 川端, 猛夫 |
キーワード: | ellagitannin glycosidation organocatalysis regioselectivity total synthesis |
発行日: | 18-May-2015 |
出版者: | wiley |
誌名: | Angewandte Chemie |
巻: | 54 |
号: | 21 |
開始ページ: | 6177 |
終了ページ: | 6180 |
抄録: | Short total syntheses of natural glycosides (ellagitannins) were performed through sequential and regioselective functionalization of the hydroxy groups of unprotected glucose. The key reactions are β-selective glycosidation of a gallic acid derivative by using unprotected glucose as a glycosyl donor and catalyst-controlled regioselective introduction of a galloyl group into the inherently less reactive hydroxy group of the glucoside. |
記述: | Article first published online: 9 APR 2015 |
著作権等: | This is the peer reviewed version of the following article:Takeuchi, H., Mishiro, K., Ueda, Y., Fujimori, Y., Furuta, T. and Kawabata, T. (2015), Total Synthesis of Ellagitannins through Regioselective Sequential Functionalization of Unprotected Glucose. Angew. Chem. Int. Ed., 54: 6177–6180, which has been published in final form at http://dx.doi.org/10.1002/anie.201500700. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. The full-text file will be made open to the public on 9 APR 2016 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
URI: | http://hdl.handle.net/2433/202533 |
DOI(出版社版): | 10.1002/anie.201500700 |
PubMed ID: | 25865579 |
出現コレクション: | 学術雑誌掲載論文等 |
このリポジトリに保管されているアイテムはすべて著作権により保護されています。