|Title:||Total Synthesis of Ellagitannins through Regioselective Sequential Functionalization of Unprotected Glucose.|
|Author's alias:||川端, 猛夫|
|Journal title:||Angewandte Chemie|
|Abstract:||Short total syntheses of natural glycosides (ellagitannins) were performed through sequential and regioselective functionalization of the hydroxy groups of unprotected glucose. The key reactions are β-selective glycosidation of a gallic acid derivative by using unprotected glucose as a glycosyl donor and catalyst-controlled regioselective introduction of a galloyl group into the inherently less reactive hydroxy group of the glucoside.|
|Description:||Article first published online: 9 APR 2015|
|Rights:||This is the peer reviewed version of the following article:Takeuchi, H., Mishiro, K., Ueda, Y., Fujimori, Y., Furuta, T. and Kawabata, T. (2015), Total Synthesis of Ellagitannins through Regioselective Sequential Functionalization of Unprotected Glucose. Angew. Chem. Int. Ed., 54: 6177–6180, which has been published in final form at http://dx.doi.org/10.1002/anie.201500700. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.|
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|Appears in Collections:||Journal Articles|
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