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Title: Recent progress of optical functional nanomaterials based on organoboron complexes with β-diketonate, ketoiminate and diiminate
Authors: Tanaka, Kazuo  kyouindb  KAKEN_id
Chujo, Yoshiki
Author's alias: 田中, 一生
中條, 善樹
Issue Date: 6-Nov-2015
Publisher: Nature Publishing Group
Journal title: NPG Asia Materials
Volume: 7
Thesis number: e223
Abstract: The synthesis and application of organoboron complexes are a highly relevant topic owng to their unique characteristics. Based on their emissive properties, these complexes have been used to make novel optical materials and devices; boron β-diketonate is a simple and robust organoboron complex. From a series of recent studies, unique and versatile optical properties have been reported. In this review, we introduce the results of primarily recent studies on boron diketonate and related compounds containing polymers and particularly explain their optical properties. Initially, the multi-emission of boron diketonate derivatives and its application to biotechnology are explained. Next, the formation of nanostructures and its emission properties are demonstrated. The modulation of optical properties by mechanical stress is also presented. Finally, recent progress in the development of solid-emissive materials are shown with boron diketonates and their derivatives, which have aggregation-induced emission properties. The versatility of boron diketonates as a building block for the preparation of functional optical materials is the focus of this review.
Rights: This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
URI: http://hdl.handle.net/2433/207597
DOI(Published Version): 10.1038/am.2015.118
Appears in Collections:Journal Articles

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