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タイトル: | Spectroscopic study on deuterated benzenes. I. Microwave spectra and molecular structure in the ground state. |
著者: | Kunishige, Sachi Katori, Toshiharu Baba, Masaaki Nakajima, Masakazu Endo, Yasuki |
著者名の別形: | 馬場, 正昭 |
発行日: | 28-Dec-2015 |
出版者: | AIP Publishing |
誌名: | The Journal of chemical physics |
巻: | 143 |
号: | 24 |
論文番号: | 244302 |
抄録: | We observed microwave absorption spectra of some deuterated benzenes and accurately determined therotational constants of all H/D isotopomers in the ground vibrational state. Using synthetic analysis assuming that all bond angles are 120°, the mean bond lengths were obtained to be r[0](C–C) = 1.3971 Å and r[0](C–H) =r[0](C–D) = 1.0805 Å. It has been concluded that the effect of deuterium substitution on the molecular structureis negligibly small and that the mean bond lengths of C–H and C–D are identical unlike small aliphatic hydrocarbons, in which r[0](C–D) is about 5 mÅ shorter than r[0](C–H). It is considered that anharmonicity is very small in the C–H stretching vibration of aromatic hydrocarbons. |
著作権等: | © 2015 AIP Publishing. This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. The following article may be found at http://scitation.aip.org/content/aip/journal/jcp/143/24/10.1063/1.4937949. |
URI: | http://hdl.handle.net/2433/207681 |
DOI(出版社版): | 10.1063/1.4937949 |
PubMed ID: | 26723666 |
出現コレクション: | 学術雑誌掲載論文等 |
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