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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| ncomms6851.pdf | 1.4 MB | Adobe PDF | 見る/開く |
| タイトル: | Porous coordination polymers with ubiquitous and biocompatible metals and a neutral bridging ligand |
| 著者: | Noro, Shin Ichiro Mizutani, Junya Hijikata, Yuh Matsuda, Ryotaro Sato, Hiroshi Kitagawa, Susumu    https://orcid.org/0000-0001-6956-9543 (unconfirmed)Sugimoto, Kunihisa https://orcid.org/0000-0002-0103-8153 (unconfirmed)Inubushi, Yasutaka Kubo, Kazuya Nakamura, Takayoshi |
| 著者名の別形: | 松田, 亮太郎 北川, 進 |
| キーワード: | Chemical sciences Inorganic chemistry Materials science |
| 発行日: | 16-Jan-2015 |
| 出版者: | Nature Publishing Group |
| 誌名: | Nature Communications |
| 巻: | 6 |
| 論文番号: | 5851 |
| 抄録: | The design of inexpensive and less toxic porous coordination polymers (PCPs) that show selective adsorption or high adsorption capacity is a critical issue in research on applicable porous materials. Although use of Group II magnesium(II) and calcium(II) ions as building blocks could provide cheaper materials and lead to enhanced biocompatibility, examples of magnesium(II) and calcium(II) PCPs are extremely limited compared with commonly used transition metal ones, because neutral bridging ligands have not been available for magnesium(II) and calcium(II) ions. Here we report a rationally designed neutral and charge-polarized bridging ligand as a new partner for magnesium(II) and calcium(II) ions. The three-dimensional magnesium(II) and calcium(II) PCPs synthesized using such a neutral ligand are stable and show selective adsorption and separation of carbon dioxide over methane at ambient temperature. This synthetic approach allows the structural diversification of Group II magnesium(II) and calcium(II) PCPs. |
| 著作権等: | This work is licensed under a Creative Commons Attribution 3.0 Unported License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/3.0/ |
| URI: | http://hdl.handle.net/2433/210228 |
| DOI(出版社版): | 10.1038/ncomms6851 |
| PubMed ID: | 25592677 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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