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Title: A light-driven three-dimensional plasmonic nanosystem that translates molecular motion into reversible chiroptical function
Authors: Kuzyk, Anton
Yang, Yangyang
Duan, Xiaoyang
Stoll, Simon
Govorov, Alexander O.
Sugiyama, Hiroshi  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0001-8923-5946 (unconfirmed)
Endo, Masayuki  KAKEN_id
Liu, Na
Author's alias: 遠藤, 政幸
Keywords: Physical sciences
Biotechnology
Materials science
Nanotechnology
Issue Date: 2-Feb-2016
Publisher: Nature Publishing Group
Journal title: Nature Communications
Volume: 7
Thesis number: 10591
Abstract: Nature has developed striking light-powered proteins such as bacteriorhodopsin, which can convert light energy into conformational changes for biological functions. Such natural machines are a great source of inspiration for creation of their synthetic analogues. However, synthetic molecular machines typically operate at the nanometre scale or below. Translating controlled operation of individual molecular machines to a larger dimension, for example, to 10-100 nm, which features many practical applications, is highly important but remains challenging. Here we demonstrate a light-driven plasmonic nanosystem that can amplify the molecular motion of azobenzene through the host nanostructure and consequently translate it into reversible chiroptical function with large amplitude modulation. Light is exploited as both energy source and information probe. Our plasmonic nanosystem bears unique features of optical addressability, reversibility and modulability, which are crucial for developing all-optical molecular devices with desired functionalities.
Rights: This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
URI: http://hdl.handle.net/2433/210230
DOI(Published Version): 10.1038/ncomms10591
PubMed ID: 26830310
Appears in Collections:Journal Articles

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