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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| c5sc01266j.pdf | 390.16 kB | Adobe PDF | 見る/開く |
完全メタデータレコード
| DCフィールド | 値 | 言語 |
|---|---|---|
| dc.contributor.author | Sasamori, Takahiro | en |
| dc.contributor.author | Sugahara, Tomohiro | en |
| dc.contributor.author | Agou, Tomohiro | en |
| dc.contributor.author | Sugamata, Koh | en |
| dc.contributor.author | Guo, Jing Dong | en |
| dc.contributor.author | Nagase, Shigeru | en |
| dc.contributor.author | Tokitoh, Norihiro | en |
| dc.contributor.alternative | 笹森, 貴裕 | ja |
| dc.contributor.alternative | 吾郷, 友宏 | ja |
| dc.contributor.alternative | 永瀬, 茂 | ja |
| dc.contributor.alternative | 時任, 宣博 | ja |
| dc.date.accessioned | 2016-05-12T07:03:44Z | - |
| dc.date.available | 2016-05-12T07:03:44Z | - |
| dc.date.issued | 2015-06-24 | - |
| dc.identifier.issn | 2041-6539 | - |
| dc.identifier.uri | http://hdl.handle.net/2433/210578 | - |
| dc.description.abstract | Reaction of the stable digermyne BbtGeGeBbt (Bbt = 2, 6-[CH(SiMe<inf>3</inf>)<inf>2</inf>]<inf>2</inf>-4-[C(SiMe<inf>3</inf>)<inf>3</inf>]-C<inf>6</inf>H<inf>2</inf>) with ethylene initially afforded the corresponding 1, 2-digermacyclobutene. Depending on the reaction conditions applied, further reaction of this 1, 2-digermacyclobutene with ethylene furnished two different reaction products: a 1, 4-digermabicyclo[2.2.0]hexane or a bis(germiranyl)ethane. Combined experimental and theoretical results suggested that the 1, 4-digermabicyclo[2.2.0]hexane and the bis(germiranyl)ethane are the thermodynamic and kinetic reaction products, respectively. A reaction mechanism in agreement with these results was proposed. | en |
| dc.format.mimetype | application/pdf | - |
| dc.language.iso | eng | - |
| dc.publisher | Royal Society of Chemistry | en |
| dc.rights | © The Royal Society of Chemistry 2015. | en |
| dc.rights | This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. | en |
| dc.title | Reaction of a diaryldigermyne with ethylene | en |
| dc.type | journal article | - |
| dc.type.niitype | Journal Article | - |
| dc.identifier.jtitle | Chemical Science | en |
| dc.identifier.volume | 6 | - |
| dc.identifier.spage | 5526 | - |
| dc.identifier.epage | 5530 | - |
| dc.relation.doi | 10.1039/c5sc01266j | - |
| dc.textversion | publisher | - |
| dc.identifier.pmid | 28757948 | - |
| dcterms.accessRights | open access | - |
| 出現コレクション: | 学術雑誌掲載論文等 | |
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