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|---|---|---|---|---|
| am201617a.pdf | 834.81 kB | Adobe PDF | 見る/開く |
| タイトル: | The relationship between magneto-optical properties and molecular chirality |
| 著者: | Wada, Satoshi Kitagawa, Yuichi Nakanishi, Takayuki Fushimi, Koji Morisaki, Yasuhiro Fujita, Koji    https://orcid.org/0000-0002-1700-0889 (unconfirmed)Konishi, Katsuaki Tanaka, Katsuhisa https://orcid.org/0000-0002-1409-2802 (unconfirmed)Chujo, Yoshiki Hasegawa, Yasuchika |
| 著者名の別形: | 藤田, 晃司 田中, 勝久 中條, 善樹 |
| 発行日: | 25-Mar-2016 |
| 出版者: | Springer Nature |
| 誌名: | NPG ASIA MATERIALS |
| 巻: | 8 |
| 号: | 3 |
| 開始ページ: | 1 |
| 終了ページ: | 6 |
| 論文番号: | e251 |
| 抄録: | The chiral nonanuclear Tb(III) clusters [Tb9(sal-(R)-Bt)16(μ-OH)10]+[NO3]− (Tb-(R)-Bt: sal-(R)-Bt=(R)-2-butyl salicylate) and [Tb9 (sal-(S)-Bt)16(μ-OH)10]+[NO3]− (Tb-(S)-Bt: sal-(S)-Bt=(S)-2-butyl salicylate) were found to exhibit a unique magneto-optical property: the Faraday effect. The clusters were composed of 9 Tb(III) ions bridged by 10 μ-OHs and 16 chiral salicylic acid esters. The Faraday rotation angle of Tb-(R)-Bt was greater than that of Tb-(S)-Bt, indicating that the Faraday effect was affected by the chirality of the Tb(III) clusters. The chiroptical properties of the Tb(III) clusters were estimated using circular dichroism and circularly polarized luminescence. In this study, a new finding concerning chiral magneto-optical properties was investigated. |
| 記述: | Supplementary Information accompanies the paper on the NPG Asia Materials website (http://www.nature.com/am) |
| 著作権等: | This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. |
| URI: | http://hdl.handle.net/2433/217451 |
| DOI(出版社版): | 10.1038/am.2016.17 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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