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タイトル: | Heterogeneous-surface-mediated crystallization control |
著者: | Zhou, Shifeng Zheng, Binbin Shimotsuma, Yasuhiko https://orcid.org/0000-0003-0588-3167 (unconfirmed) Lu, Yunhao Guo, Qiangbing Nishi, Masayuki https://orcid.org/0000-0002-9387-2152 (unconfirmed) Shimizu, Masahiro https://orcid.org/0000-0002-9948-891X (unconfirmed) Miura, Kiyotaka https://orcid.org/0000-0001-6199-7113 (unconfirmed) Hirao, Kazuyuki Qiu, Jianrong |
著者名の別形: | 三浦, 清貴 下間, 靖彦 西, 正之 清水, 雅弘 平尾, 一之 |
発行日: | 18-Mar-2016 |
出版者: | NATURE PUBLISHING GROUP |
誌名: | NPG ASIA MATERIALS |
巻: | 8 |
号: | 3 |
論文番号: | e245 |
抄録: | The crystallization of matter at interfaces has long been a significant issue in science and technology, but surface-directed crystallization with controlled kinetics remains a matter of challenge. Here, we demonstrate a conceptual novel mechanism to steer liquid?solid phase transformation at interfaces by tailoring the chemical and structural inhomogeneity of a glass substrate through self-limited nanocrystallization of the glassy phase. Importantly, this approach enables large-scale development of metastable crystallization products, such as nanowire membranes. The thorough studies of the intermediate stages of crystallization reveal a unique cooperative mechanism in which the intricate interplays between inherent nanoscale forces and unique heterogeneous surfaces contribute to the mesoscale structural transformation from isolated units to superstructures. We further show that the constructed superstructures offer unprecedented opportuntities for the development of functional membrane systems possessing the combination of robust trace-detection performance and molecular trapping function. These findings not only present clear technological implications, but also provide an improved understanding of the fundamental mechanisms of surface-induced geological and biological processes. |
著作権等: | This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, userswill need to obtain permission fromthe license holder to reproduce the material. To view a copy of this license, visit http:// creativecommons.org/licenses/by/4.0/ |
URI: | http://hdl.handle.net/2433/218410 |
DOI(出版社版): | 10.1038/am.2016.15 |
出現コレクション: | 学術雑誌掲載論文等 |
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