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dc.contributor.author | Diring, Stéphane | en |
dc.contributor.author | Carné-Sánchez, Arnau | en |
dc.contributor.author | Zhang, Ji Cheng | en |
dc.contributor.author | Ikemura, Shuya | en |
dc.contributor.author | Kim, Chiwon | en |
dc.contributor.author | Inaba, Hiroshi | en |
dc.contributor.author | Kitagawa, Susumu | en |
dc.contributor.author | Furukawa, Shuhei | en |
dc.contributor.alternative | 北川, 進 | ja |
dc.contributor.alternative | 古川, 修平 | ja |
dc.date.accessioned | 2017-03-13T02:12:24Z | - |
dc.date.available | 2017-03-13T02:12:24Z | - |
dc.date.issued | 2017 | - |
dc.identifier.issn | 2041-6539 | - |
dc.identifier.uri | http://hdl.handle.net/2433/218793 | - |
dc.description.abstract | A new carbon monoxide (CO)-releasing material has been developed by embedding a manganese carbonyl complex, MnBr(bpydc)(CO)3 (bpydc = 5, 5′-dicarboxylate-2, 2′-bipyridine) into a highly robust Zr(iv)-based metal-organic framework (MOF). Efficient and controllable CO-release was achieved under exposure to low intensity visible light. Size-controllable nanocrystals of the photoactive MOF were obtained and their CO-releasing properties were correlated with their crystal sizes. The photoactive crystals were processed into cellular substrates with a biocompatible polymer matrix, and the light-induced delivery of CO and its subsequent cellular uptake were monitored using a fluorescent CO-probe. The results discussed here demonstrate a new opportunity to use MOFs as macromolecular scaffolds towards CO-releasing materials and the advantage of MOFs for high CO payloads, which is essential in future therapeutic applications. | en |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Royal Society of Chemistry (RSC) | en |
dc.rights | © The Royal Society of Chemistry. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. | en |
dc.title | Light responsive metal-organic frameworks as controllable CO-releasing cell culture substrates | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.ncid | AA12555653 | - |
dc.identifier.jtitle | Chemical Science | en |
dc.identifier.volume | 8 | - |
dc.identifier.spage | 2381 | - |
dc.identifier.epage | 2386 | - |
dc.relation.doi | 10.1039/c6sc04824b | - |
dc.textversion | publisher | - |
dc.address | Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University | en |
dc.address | Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University | en |
dc.identifier.pmid | 28451343 | - |
dcterms.accessRights | open access | - |
dc.identifier.pissn | 2041-6520 | - |
dc.identifier.eissn | 2041-6539 | - |
出現コレクション: | 学術雑誌掲載論文等 |
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