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dc.contributor.author | Nishino, Kenta | en |
dc.contributor.author | Uemura, Kyoya | en |
dc.contributor.author | Gon, Masayuki | en |
dc.contributor.author | Tanaka, Kazuo | en |
dc.contributor.author | Chujo, Yoshiki | en |
dc.contributor.alternative | 上村, 京也 | ja |
dc.contributor.alternative | 権, 正行 | ja |
dc.contributor.alternative | 田中, 一生 | ja |
dc.contributor.alternative | 中條, 善樹 | ja |
dc.date.accessioned | 2018-08-21T06:19:51Z | - |
dc.date.available | 2018-08-21T06:19:51Z | - |
dc.date.issued | 2017-11-19 | - |
dc.identifier.issn | 1420-3049 | - |
dc.identifier.uri | http://hdl.handle.net/2433/233935 | - |
dc.description.abstract | The enhancement of aggregation-induced emission (AIE) is presented on the basis of the strategy for improving solid-state luminescence by employing multiple o-carborane substituents. We synthesized the modified triphenylamines with various numbers of o-carborane units and compared their optical properties. From the optical measurements, the emission bands from the twisted intramolecular charge transfer (TICT) state were obtained from the modified triphenylamines. It was notable that emission efficiencies of the multi-substituted triphenylamines including two or three o-carborane units were enhanced 6- to 8-fold compared to those of the mono-substituted triphenylamine. According to mechanistic studies, it was proposed that the single o-carborane substitution can load the AIE property via the TICT mechanism. It was revealed that the additional o-carborane units contribute to improving solid-state emission by suppressing aggregation-caused quenching (ACQ). Subsequently, intense AIEs were obtained. This paper presents a new role of the o-carborane substituent in the enhancement of AIEs. | en |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | MDPI AG | en |
dc.rights | © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0). | en |
dc.subject | carborane | en |
dc.subject | twisted intramolecular charge transfer | en |
dc.subject | triphenylamine | en |
dc.title | Enhancement of aggregation-induced emission by introducing multiple o-carborane substitutions into triphenylamine | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.jtitle | Molecules | en |
dc.identifier.volume | 22 | - |
dc.identifier.issue | 11 | - |
dc.relation.doi | 10.3390/molecules22112009 | - |
dc.textversion | publisher | - |
dc.identifier.artnum | 2009 | - |
dc.address | Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University | en |
dc.address | Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University | en |
dc.address | Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University | en |
dc.address | Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University | en |
dc.address | Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University | en |
dc.identifier.pmid | 29156590 | - |
dcterms.accessRights | open access | - |
dc.identifier.eissn | 1420-3049 | - |
出現コレクション: | 学術雑誌掲載論文等 |
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