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s41598-018-28311-2.pdf | 3.09 MB | Adobe PDF | 見る/開く |
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dc.contributor.author | Yamamoto, Yasuyuki | en |
dc.contributor.author | Nishimura, Yushi | en |
dc.contributor.author | Tokonami, Shiho | en |
dc.contributor.author | Fukui, Norihito | en |
dc.contributor.author | Tanaka, Takayuki | en |
dc.contributor.author | Osuka, Atsuhiro | en |
dc.contributor.author | Yorimitsu, Hideki | en |
dc.contributor.author | Iida, Takuya | en |
dc.contributor.alternative | 福井, 識人 | ja |
dc.contributor.alternative | 田中, 隆行 | ja |
dc.contributor.alternative | 大須賀, 篤弘 | ja |
dc.contributor.alternative | 依光, 英樹 | ja |
dc.date.accessioned | 2018-11-20T07:55:50Z | - |
dc.date.available | 2018-11-20T07:55:50Z | - |
dc.date.issued | 2018-07-23 | - |
dc.identifier.issn | 2045-2322 | - |
dc.identifier.uri | http://hdl.handle.net/2433/235238 | - |
dc.description.abstract | Porphyrin-based molecules play an important role in natural biological systems such as photosynthetic antennae and haemoglobin. Recent organic chemistry provides artificial porphyrin-based molecules having unique electronic and optical properties, which leads to wide applications in material science. Here, we successfully produced many macroscopically anisotropic structures consisting of porphyrin dimers by light-induced solvothermal assembly with smooth evaporation in a confined volatile organic solvent. Light-induced fluid flow around a bubble on a gold nanofilm generated a sub-millimetre radial assembly of the tens-micrometre-sized petal-like structures. The optical properties of the petal-like structures depend on the relative angle between their growth direction and light polarisation, as confirmed by UV-visible extinction and the Raman scattering spectroscopy analyses, being dramatically different from those of structures obtained by natural drying. Thus, our findings pave the way to the production of structures and polycrystals with unique characteristics from various organic molecules. | en |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Springer Nature | en |
dc.rights | © The Author(s) 2018. This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. | en |
dc.title | Macroscopically Anisotropic Structures Produced by Light-induced Solvothermal Assembly of Porphyrin Dimers | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.jtitle | Scientific Reports | en |
dc.identifier.volume | 8 | - |
dc.relation.doi | 10.1038/s41598-018-28311-2 | - |
dc.textversion | publisher | - |
dc.identifier.artnum | 11108 | - |
dc.address | Department of Physics, Graduate School of Science, Osaka Prefecture University・Research Institute for Light-induced Acceleration System (RILACS), Osaka Prefecture University・Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University | en |
dc.address | Department of Physics, Graduate School of Science, Osaka Prefecture University・Research Institute for Light-induced Acceleration System (RILACS), Osaka Prefecture University・Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University・Division of Molecular Materials Science, Graduate School of Science Osaka City University | en |
dc.address | Research Institute for Light-induced Acceleration System (RILACS), Osaka Prefecture University・Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University | en |
dc.address | Department of Chemistry, Graduate School of Science, Kyoto University・Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University | en |
dc.address | Department of Chemistry, Graduate School of Science, Kyoto University | en |
dc.address | Department of Chemistry, Graduate School of Science, Kyoto University | en |
dc.address | Department of Chemistry, Graduate School of Science, Kyoto University | en |
dc.address | Department of Physics, Graduate School of Science, Osaka Prefecture University・Research Institute for Light-induced Acceleration System (RILACS), Osaka Prefecture University | en |
dc.identifier.pmid | 30038403 | - |
dcterms.accessRights | open access | - |
datacite.awardNumber | JP15H03010 | - |
datacite.awardNumber | JP26286029 | - |
datacite.awardNumber | JP17H00856 | - |
datacite.awardNumber | JP15K14697 | - |
datacite.awardNumber | JP16H06507 | - |
datacite.awardNumber | JP25107002 | - |
datacite.awardNumber | JP18J13307 | - |
datacite.awardNumber | JP15J09975 | - |
datacite.awardNumber | JP15J01145 | - |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
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