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dc.contributor.author | Craig, Gavin A. | en |
dc.contributor.author | Larpent, Patrick | en |
dc.contributor.author | Kusaka, Shinpei | en |
dc.contributor.author | Matsuda, Ryotaro | en |
dc.contributor.author | Kitagawa, Susumu | en |
dc.contributor.author | Furukawa, Shuhei | en |
dc.contributor.alternative | 日下, 心平 | ja |
dc.contributor.alternative | 松田, 亮太郎 | ja |
dc.contributor.alternative | 北川, 進 | ja |
dc.contributor.alternative | 古川, 修平 | ja |
dc.date.accessioned | 2018-11-26T05:02:45Z | - |
dc.date.available | 2018-11-26T05:02:45Z | - |
dc.date.issued | 2018-08-31 | - |
dc.identifier.issn | 2041-6520 | - |
dc.identifier.uri | http://hdl.handle.net/2433/235350 | - |
dc.description.abstract | Gate-opening gas sorption is known for metal–organic frameworks, and is associated with structural flexibility and advantageous properties for sensing and gas uptake. Here, we show that gate-opening is also possible for metal–organic polyhedra (MOPs), and depends on the molecular organisation in the lattice. Thanks to the solubility of MOPs, several interchangeable solvatomorphs of a lantern-type MOP were synthesised via treatment with different solvents. One phase obtained through use of methanol induced a gate-opening effect in the lattice in response to carbon dioxide uptake. The sorption process was thoroughly investigated with in situ powder X-ray diffraction and simultaneous adsorption experiments. Meanwhile, solution processing of this flexible phase using THF led to a permanently porous phase without a gate-opening effect. Furthermore, we find that we can change the metallic composition of the MOP, and yet retain flexibility. By showing that gate-opening can be switched on and off depending on the solvent of crystallisation, these findings have implications for the solution-based processing of MOPs. | en |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Royal Society of Chemistry (RSC) | en |
dc.rights | This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material. | en |
dc.title | Switchable gate-opening effect in metal–organic polyhedra assemblies through solution processing | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.jtitle | Chemical Science | en |
dc.identifier.volume | 9 | - |
dc.identifier.issue | 31 | - |
dc.identifier.spage | 6463 | - |
dc.identifier.epage | 6469 | - |
dc.relation.doi | 10.1039/C8SC02263A | - |
dc.textversion | publisher | - |
dc.address | Institute for Integrated Cell-Material Science (WPI-iCeMS), Kyoto University | en |
dc.address | Institute for Integrated Cell-Material Science (WPI-iCeMS), Kyoto University | en |
dc.address | Institute for Integrated Cell-Material Science (WPI-iCeMS), Kyoto University | en |
dc.address | Institute for Integrated Cell-Material Science (WPI-iCeMS), Kyoto University | en |
dc.address | Institute for Integrated Cell-Material Science (WPI-iCeMS), Kyoto University | en |
dc.address | Institute for Integrated Cell-Material Science (WPI-iCeMS), Kyoto University・Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University | en |
dc.identifier.pmid | 30310576 | - |
dcterms.accessRights | open access | - |
datacite.awardNumber | 17H05367 | - |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
出現コレクション: | 学術雑誌掲載論文等 |
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