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dc.contributor.author | Naniwa, Shimpei | en |
dc.contributor.author | Tyagi, Akanksha | en |
dc.contributor.author | Yamamoto, Akira | en |
dc.contributor.author | Yoshida, Hisao | en |
dc.contributor.alternative | 浪花, 晋平 | ja |
dc.contributor.alternative | 山本, 旭 | ja |
dc.contributor.alternative | 吉田, 寿雄 | ja |
dc.date.accessioned | 2018-12-10T07:08:19Z | - |
dc.date.available | 2018-12-10T07:08:19Z | - |
dc.date.issued | 2018-12-07 | - |
dc.identifier.issn | 1463-9084 | - |
dc.identifier.uri | http://hdl.handle.net/2433/235622 | - |
dc.description.abstract | Upon photoirradiation with visible light, a pyridine molecule adsorbed on a TiO₂ surface can be photoexcited to give a pyridine radical cation via ligand-to-metal charge transfer (LMCT) between pyridine and titanium. This leads to dehydrogenative cross-coupling (DCC) between pyridine and cyclohexane with concomitant hydrogen evolution. Since the radical cation can selectively oxidize cyclohexane to a cyclohexyl radical, the cross-coupling between pyridine and cyclohexane proceeds with higher selectivity compared with that in photocatalysis by TiO₂ under UV irradiation. | en |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Royal Society of Chemistry (RSC) | en |
dc.rights | This is the accepted manuscript of the article, which has been published in final form at https://doi.org/10.1039/C8CP04292F. | en |
dc.rights | The full-text file will be made open to the public on 18 August 2019 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. | en |
dc.rights | この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | ja |
dc.rights | This is not the published version. Please cite only the published version. | en |
dc.title | Visible-light photoexcitation of pyridine surface complex, leading to selective dehydrogenative cross-coupling with cyclohexane | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.jtitle | Physical Chemistry Chemical Physics | en |
dc.identifier.volume | 20 | - |
dc.identifier.issue | 45 | - |
dc.identifier.spage | 28375 | - |
dc.identifier.epage | 28381 | - |
dc.relation.doi | 10.1039/c8cp04292f | - |
dc.textversion | author | - |
dc.address | Graduate School of Human and Environmental Studies, Kyoto University | en |
dc.address | Graduate School of Human and Environmental Studies, Kyoto University | en |
dc.address | Graduate School of Human and Environmental Studies, Kyoto University・Elements Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University | en |
dc.address | Graduate School of Human and Environmental Studies, Kyoto University・Elements Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University | en |
dc.identifier.pmid | 30182096 | - |
dcterms.accessRights | open access | - |
datacite.date.available | 2019-08-18 | - |
出現コレクション: | 学術雑誌掲載論文等 |
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