Synthesis of Octahydro- and Decahydroquinolines by a One-Pot Cascade Reaction of Tetrasubstituted Enecarbamate

Kurose, Tomohiro; Tsukano, Chihiro; Takemoto, Yoshiji

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http://hdl.handle.net/2433/235944

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dc.contributor.author	Kurose, Tomohiro	en
dc.contributor.author	Tsukano, Chihiro	en
dc.contributor.author	Takemoto, Yoshiji	en
dc.contributor.alternative	黒瀬, 朋浩	ja
dc.contributor.alternative	塚野, 千尋	ja
dc.contributor.alternative	竹本, 佳司	ja
dc.date.accessioned	2019-01-07T07:42:56Z	-
dc.date.available	2019-01-07T07:42:56Z	-
dc.date.issued	2017-09-15	-
dc.identifier.issn	1523-7060	-
dc.identifier.uri	http://hdl.handle.net/2433/235944	-
dc.description.abstract	A transition-metal-catalyzed cyclopropanation followed by ring opening was investigated for the synthesis of octahydroquinolines 4 and decahydroquinolines 5 having a quaternary carbon center at the angular position, which are core structures of the fawcettimine-type alkaloids. A tandem reaction was also established for the synthesis of decahydroquinolines 5 and the tricyclic compound 6 through an iminium ion intermediate, readily produced by acidic treatment of cyclopropane 2.	en
dc.format.mimetype	application/pdf	-
dc.language.iso	eng	-
dc.publisher	American Chemical Society	en
dc.rights	This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.7b02122.	en
dc.rights	この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。	ja
dc.rights	This is not the published version. Please cite only the published version.	en
dc.title	Synthesis of Octahydro- and Decahydroquinolines by a One-Pot Cascade Reaction of Tetrasubstituted Enecarbamate	en
dc.type	journal article	-
dc.type.niitype	Journal Article	-
dc.identifier.jtitle	Organic Letters	en
dc.identifier.volume	19	-
dc.identifier.issue	18	-
dc.identifier.spage	4762	-
dc.identifier.epage	4765	-
dc.relation.doi	10.1021/acs.orglett.7b02122	-
dc.textversion	author	-
dc.address	Graduate School of Pharmaceutical Sciences, Kyoto University	en
dc.address	Graduate School of Pharmaceutical Sciences, Kyoto University	en
dc.address	Graduate School of Pharmaceutical Sciences, Kyoto University	en
dc.identifier.pmid	28880096	-
dcterms.accessRights	open access	-
datacite.awardNumber	JP17H05051	-
jpcoar.funderName	日本学術振興会	ja
jpcoar.funderName.alternative	Japan Society for the Promotion of Science (JSPS)	en
出現コレクション:	学術雑誌掲載論文等

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