このアイテムのアクセス数: 3

このアイテムのファイル:
ファイル 記述 サイズフォーマット 
cpb.c16-00439.pdf720.42 kBAdobe PDF見る/開く
完全メタデータレコード
DCフィールド言語
dc.contributor.authorNanjo, Takeshi
dc.contributor.authorTsukano, Chihiro
dc.contributor.authorTakemoto, Yoshiji
dc.contributor.alternative南條, 毅
dc.contributor.alternative塚野, 千尋
dc.contributor.alternative竹本, 佳司
dc.date.accessioned2019-01-08T05:19:55Z-
dc.date.available2019-01-08T05:19:55Z-
dc.date.issued2016-09-01
dc.identifier.issn1347-5223
dc.identifier.urihttp://hdl.handle.net/2433/235953-
dc.description.abstractThe synthesis of benzocyclobutenes from simple arenes bearing a directing group was investigated via the palladium-catalyzed cyclization of norbornene derivatives. This approach allowed for the facile construction of benzocyclobutenes along with the double functionalization of the C - H bonds at the positions ortho and meta to the directing group. This result shows that the key palladacyclopentene intermediate in the Catellani reaction can be prepared by the directed double ortho C - H activation of the substrate. The results of this study also revealed that the combination of an N-protected amino acid with benzoquinone (BQ) was effective for this transformation.
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherPharmaceutical Society of Japan
dc.rights許諾条件に基づいて掲載しています。
dc.subjectC–H functionalization
dc.subjectbenzocyclobutene
dc.subjectpalladium
dc.subjectdirecting group
dc.subjectdouble functionalization
dc.titlePalladium-catalyzed double C - H functionalization of arenes at the positions ortho and meta to their directing group: Concise synthesis of benzocyclobutenes
dc.type.niitypeJournal Article
dc.identifier.ncidAA00602100
dc.identifier.jtitleChemical and Pharmaceutical Bulletin
dc.identifier.volume64
dc.identifier.issue9
dc.identifier.spage1384
dc.identifier.epage1392
dc.relation.doi10.1248/cpb.c16-00439
dc.textversionpublisher
dc.addressGraduate School of Pharmaceutical Sciences, Kyoto University
dc.addressGraduate School of Pharmaceutical Sciences, Kyoto University
dc.addressGraduate School of Pharmaceutical Sciences, Kyoto University
dc.relation.NAIDhttps://ci.nii.ac.jp/naid/130005261606
出現コレクション:学術雑誌掲載論文等

アイテムの簡略レコードを表示する

Export to RefWorks


出力フォーマット 


このリポジトリに保管されているアイテムはすべて著作権により保護されています。