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molecules24030642.pdf | 2.3 MB | Adobe PDF | 見る/開く |
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dc.contributor.author | Ueta, Kento | en |
dc.contributor.author | Tanaka, Takayuki | en |
dc.contributor.author | Osuka, Atsuhiro | en |
dc.contributor.alternative | 植田, 賢人 | ja |
dc.contributor.alternative | 田中, 隆行 | ja |
dc.contributor.alternative | 大須賀, 篤弘 | ja |
dc.date.accessioned | 2019-03-05T02:36:25Z | - |
dc.date.available | 2019-03-05T02:36:25Z | - |
dc.date.issued | 2019-02-01 | - |
dc.identifier.issn | 1420-3049 | - |
dc.identifier.uri | http://hdl.handle.net/2433/236665 | - |
dc.description.abstract | A corrole is a tetrapyrrolic macrocycle known as a ring-contracted porphyrinoid. Despite the progress of the synthetic chemistry of meso-aryl-substituted corroles since the early 2000s, meso-heteroatom-substituted corroles have been scarcely reported. Herein we report that the SNAr-type substitution reaction of a meso-chlorocorrole silver complex with diphenylamine or carbazole in the presence of NaH as a base produced meso-aminocorroles. The structures, ultraviolet–visible spectroscopy (UV/Vis), and emission spectra of these meso-aminocorroles were discussed. Furthermore, the oxidation reaction of a meso-diphenylaminocorrole was examined, which resulted in the formation of 10, 10-diethoxyisocorrole. | en |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | MDPI AG | en |
dc.rights | © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). | en |
dc.subject | corrole | en |
dc.subject | peripheral substitution | en |
dc.subject | SNAr reaction | en |
dc.subject | UV/Vis absorption | en |
dc.subject | cyclic voltammetry | en |
dc.title | Synthesis of Meso-Diarylaminocorroles via SNAr Reactions | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.jtitle | Molecules | en |
dc.identifier.volume | 24 | - |
dc.identifier.issue | 3 | - |
dc.relation.doi | 10.3390/molecules24030642 | - |
dc.textversion | publisher | - |
dc.identifier.artnum | 642 | - |
dc.address | Department of Chemistry, Graduate School of Science, Kyoto University | en |
dc.address | Department of Chemistry, Graduate School of Science, Kyoto University | en |
dc.address | Department of Chemistry, Graduate School of Science, Kyoto University | en |
dc.identifier.pmid | 30759763 | - |
dcterms.accessRights | open access | - |
datacite.awardNumber | JP25220802 | - |
datacite.awardNumber | JP26810021 | - |
datacite.awardNumber | JP18H03910 | - |
datacite.awardNumber | JP18K14199 | - |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
出現コレクション: | 学術雑誌掲載論文等 |
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