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dc.contributor.authorAdachi, Kenen
dc.contributor.authorKitada, Atushien
dc.contributor.authorFukami, Kazuhiroen
dc.contributor.authorMurase, Kuniakien
dc.contributor.alternative北田, 敦ja
dc.contributor.alternative深見, 一弘ja
dc.contributor.alternative邑瀬, 邦明ja
dc.date.accessioned2019-06-19T04:54:43Z-
dc.date.available2019-06-19T04:54:43Z-
dc.date.issued2019-06-11-
dc.identifier.issn0013-4651-
dc.identifier.urihttp://hdl.handle.net/2433/241762-
dc.description.abstractWe report a novel, cyanide-free, and low-cost displacement silver (Ag) plating bath, i.e., AgCl-dissolved highly concentrated CaCl2/LiCl aqueous solution. Compared to dilute CaCl2/LiCl solutions, this aqueous solution exhibited much higher AgCl solubility because of the high activity of Cl–; the maximum AgCl solubility was achieved at 44.4 mmol dm–3 (i.e., [Ag(I)] = 8.07 g kg−1 H2O). Smooth Ag deposits with a lusterless gray-colored appearance were successfully obtained by displacement plating on a Cu substrate. The mechanism of smooth Ag plating is discussed in terms of its electrochemical and diffusive properties.en
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherThe Electrochemical Societyen
dc.rights© The Author(s) 2019. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited.en
dc.subjectElectrodeposition - electrolessen
dc.subjectConcentrated aqueous solutionen
dc.subjectElectroless depositionen
dc.subjectSilver platingen
dc.titleCyanide-Free Displacement Silver Plating Using Highly Concentrated Aqueous Solutions of Metal Chloride Saltsen
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.jtitleJournal of The Electrochemical Societyen
dc.identifier.volume166-
dc.identifier.issue10-
dc.identifier.spageD409-
dc.identifier.epageD414-
dc.relation.doi10.1149/2.0871910jes-
dc.textversionpublisher-
dcterms.accessRightsopen access-
datacite.awardNumber19H02490-
jpcoar.funderName日本学術振興会ja
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
出現コレクション:学術雑誌掲載論文等

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