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s-0036-1588141.pdf | 427.69 kB | Adobe PDF | 見る/開く |
タイトル: | Enantioselective Synthesis of anti-β-Hydroxy-α-amino Esters via an Organocatalyzed Decarboxylative Aldol Reaction |
著者: | Takemoto, Yoshiji https://orcid.org/0000-0003-1375-3821 (unconfirmed) March, Taryn Murata, Akihiro Kobayashi, Yusuke https://orcid.org/0000-0003-3074-7378 (unconfirmed) |
著者名の別形: | 竹本, 佳司 小林, 祐輔 |
キーワード: | bifunctional organocatalyst cinchona alkaloid malonic acid half oxyester (MAHO) sulfonamide β-hydroxy-α-amino acid |
発行日: | Jul-2017 |
出版者: | Georg Thieme Verlag |
誌名: | Synlett |
巻: | 28 |
号: | 11 |
開始ページ: | 1295 |
終了ページ: | 1299 |
抄録: | The first enantioselective decarboxylative aldol addition with α-amido-substituted malonic acid half oxyesters (MAHOs) is described. The combined use of a newly designed bifunctional sulfonamide catalyst with pentafluorobenzoic acid as an additive afforded the β-hydroxy-α-amino acid derivatives in moderate to high yields and with high enantioselectivities. |
著作権等: | This is the accepted manuscript of the article, which has been published in final form at http://doi.org/10.1055/s-0036-1588141 The full-text file will be made open to the public on 2 March 2018 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
URI: | http://hdl.handle.net/2433/243148 |
DOI(出版社版): | 10.1055/s-0036-1588141 |
出現コレクション: | 学術雑誌掲載論文等 |
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