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Title: Photoactivated N-Acyliminoiodinanes Applied to Amination: an ortho-Methoxymethyl Group Stabilizes Reactive Precursors
Authors: Kobayashi, Yusuke
Masakado, Sota
Takemoto, Yoshiji
Author's alias: 小林, 祐輔
正門, 宗大
竹本, 佳司
Keywords: amination
hypervalent iodine
Issue Date: 15-Jan-2018
Publisher: Wiley
Journal title: Angewandte Chemie International Edition
Volume: 57
Issue: 3
Start page: 693
End page: 697
Abstract: N‐Acyliminoiodinanes were characterized for the first time by X‐ray structural analysis. The ortho‐methoxymethyl group and the carbonyl oxygen coordinate to the iodine atom of the iminoiodinane. Activation of the N‐acyliminoiodinane was achieved by photoirradiation at 370 nm, thereby enabling reaction with various silyl enol ethers to give α‐aminoketone derivatives in good to high yield. N‐sulfonyliminoiodinanes bearing ortho substituents were used in photoinduced amination.
Rights: This is the peer reviewed version of the following article: [Yusuke Kobayashi, Sota Masakado, Yoshiji Takemoto. Photoactivated N‐Acyliminoiodinanes Applied to Amination: an ortho‐Methoxymethyl Group Stabilizes Reactive Precursors. Angewandte Chemie International Edition, 57(3), 693-397], which has been published in final form at This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
The full-text file will be made open to the public on 09 January 2019 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
DOI(Published Version): 10.1002/anie.201710277
PubMed ID: 29193519
Appears in Collections:Journal Articles

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