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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| chem.201901690.pdf | 889.49 kB | Adobe PDF | 見る/開く |
完全メタデータレコード
| DCフィールド | 値 | 言語 |
|---|---|---|
| dc.contributor.author | Nakamura, Hugh | en |
| dc.contributor.author | Kawakami, Manami | en |
| dc.contributor.author | Tsukano, Chihiro | en |
| dc.contributor.author | Takemoto, Yoshiji | en |
| dc.contributor.alternative | 塚野, 千尋 | ja |
| dc.contributor.alternative | 竹本, 佳司 | ja |
| dc.date.accessioned | 2019-07-23T07:47:25Z | - |
| dc.date.available | 2019-07-23T07:47:25Z | - |
| dc.date.issued | 2019-07-02 | - |
| dc.identifier.issn | 0947-6539 | - |
| dc.identifier.uri | http://hdl.handle.net/2433/243179 | - |
| dc.description.abstract | A concise route for construction of the ACDE ring skeleton in calyciphylline A type alkaloids was developed using an intramolecular [5+2] cycloaddition reaction of an oxidopyrylium species bearing a tetrasubstituted olefin. Key to the success of this reaction was the combination of acid and base, which accelerated the construction of this skeleton containing a spiro ring and vicinal quaternary carbon centers. The resultant tricyclic ADE ring compound was converted to an ACDE ring model through C−H oxidation and an aza‐Wittig reaction. | en |
| dc.format.mimetype | application/pdf | - |
| dc.language.iso | eng | - |
| dc.publisher | Wiley | en |
| dc.rights | This is the peer reviewed version of the following article: H. Nakamura, M. Kawakami, C. Tsukano, Y. Takemoto, Chem. Eur. J. 2019, 25, 8701., which has been published in final form at https://doi.org/10.1002/chem.201901690. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | en |
| dc.rights | The full-text file will be made open to the public on 2 July 2020 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. | en |
| dc.rights | This is not the published version. Please cite only the published version. | en |
| dc.rights | この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | ja |
| dc.subject | [5+2] cycloaddition | en |
| dc.subject | calyciphylline A | en |
| dc.subject | daphniphyllum alkaloids | en |
| dc.subject | daphniyunnine | en |
| dc.subject | synthetic strategy | en |
| dc.title | Concise Construction of the ACDE Ring System of Calyciphylline A Type Alkaloids by a [5+2] Cycloaddition | en |
| dc.type | journal article | - |
| dc.type.niitype | Journal Article | - |
| dc.identifier.ncid | AA11076269 | - |
| dc.identifier.jtitle | Chemistry - A European Journal | en |
| dc.identifier.volume | 25 | - |
| dc.identifier.issue | 37 | - |
| dc.identifier.spage | 8701 | - |
| dc.identifier.epage | 8704 | - |
| dc.relation.doi | 10.1002/chem.201901690 | - |
| dc.textversion | author | - |
| dc.address | Graduate School of Pharmaceutical Sciences, Kyoto University | en |
| dc.address | Graduate School of Pharmaceutical Sciences, Kyoto University | en |
| dc.address | Graduate School of Pharmaceutical Sciences, Kyoto University | en |
| dc.address | Graduate School of Pharmaceutical Sciences, Kyoto University | en |
| dc.identifier.pmid | 31063603 | - |
| dcterms.accessRights | open access | - |
| datacite.date.available | 2020-07-02 | - |
| datacite.awardNumber | JP17H05051 | - |
| datacite.awardNumber | JP18H04407 | - |
| datacite.awardNumber | 16H06384 | - |
| dc.identifier.pissn | 0947-6539 | - |
| dc.identifier.eissn | 1521-3765 | - |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
| jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
| jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
| 出現コレクション: | 学術雑誌掲載論文等 | |
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