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  3. 学術雑誌掲載論文等
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dc.contributor.authorNakajima, Motoyukien
dc.contributor.authorTsukano, Chihiroen
dc.contributor.authorYasui, Motohiroen
dc.contributor.authorTakemoto, Yoshijien
dc.contributor.alternative中島, 基之ja
dc.contributor.alternative塚野, 千尋ja
dc.contributor.alternative安井, 基博ja
dc.contributor.alternative竹本, 佳司ja
dc.date.accessioned2019-07-23T08:11:36Z-
dc.date.available2019-07-23T08:11:36Z-
dc.date.issued2019-06-
dc.identifier.issn0021-8820-
dc.identifier.issn1881-1469-
dc.identifier.urihttp://hdl.handle.net/2433/243180-
dc.description.abstractCommunesins, isolated from the mycelium of a strain of Penicillium sp., are cytotoxic heptacyclic indole alkaloids bearing a bis-aminal structure and two contiguous quaternary carbon centers. Toward a total synthesis of communesin F, we synthesized a pentacyclic ABCDG ring skeleton via carboborylation of 1, 3-diene and a Friedel–Crafts-type cyclization, resulting in the formation of an azepine ring through a Bi(OTf)₃-catalyzed SN2’ reaction.en
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherNature Publishing Groupen
dc.rightsThis is the accepted manuscript of the article, which has been published in final form at https://doi.org/10.1038/s41429-019-0142-7.en
dc.rightsThe full-text file will be made open to the public on 13 September 2019 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.en
dc.rightsThis is not the published version. Please cite only the published version.en
dc.rightsこの論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。ja
dc.titleSynthesis of the ABCDG ring skeleton of communesin F based on carboborylation of 1,3-diene and Bi(OTf)₃-catalyzed cyclizationsen
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.jtitleJournal of Antibioticsen
dc.identifier.volume72-
dc.identifier.issue6-
dc.identifier.spage407-
dc.identifier.epage419-
dc.relation.doi10.1038/s41429-019-0142-7-
dc.textversionauthor-
dc.addressGraduate School of Pharmaceutical Sciences, Kyoto Universityen
dc.addressGraduate School of Pharmaceutical Sciences, Kyoto Universityen
dc.addressGraduate School of Pharmaceutical Sciences, Kyoto Universityen
dc.addressGraduate School of Pharmaceutical Sciences, Kyoto Universityen
dc.identifier.pmid30760839-
dcterms.accessRightsopen access-
datacite.date.available2019-09-13-
datacite.awardNumberJP17H05051-
datacite.awardNumberJP18H04407-
datacite.awardNumberJP16H06384-
dc.identifier.pissn0021-8820-
dc.identifier.eissn1881-1469-
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
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