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タイトル: Electrochemical performance of a lead fluoride electrode mixed with carbon in an electrolyte containing triphenylboroxine as an anion acceptor for fluoride shuttle batteries
著者: Konishi, Hiroaki
Minato, Taketoshi
Abe, Takeshi
Ogumi, Zempachi
著者名の別形: 小西, 宏明
湊, 丈俊
安部, 武志
小久見, 善八
キーワード: Fluoride shuttle battery
Anion acceptor
Triphenylboroxine
Lead fluoride
発行日: 15-Mar-2019
出版者: Elsevier BV
誌名: Materials Chemistry and Physics
巻: 226
開始ページ: 1
終了ページ: 5
抄録: In fluoride shuttle batteries (FSBs), the addition of an anion acceptor (AA) is required to dissolve the supporting electrolyte salt in an organic solvent. Based on theoretical calculations and practical experiments, the effectiveness of triphenylboroxine (TPhBX) as an AA for FSB was verified. Using an electrolyte with TPhBX as an AA, the specific capacities of the following two types of lead fluoride (PbF₂) electrodes were evaluated: (i) PbF₂ pulverized using a ball mill, (ii) pulverized PbF₂ mixed with carbon using a ball mill. The experimental results indicate that mixing PbF₂ with carbon using a ball mill increases the specific capacity of PbF₂ electrode.
著作権等: © 2019. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
The full-text file will be made open to the public on 15 March 2021 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.
この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
This is not the published version. Please cite only the published version.
URI: http://hdl.handle.net/2433/243334
DOI(出版社版): 10.1016/j.matchemphys.2019.01.006
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