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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| ejoc.202000222.pdf | 931.8 kB | Adobe PDF | 見る/開く |
| タイトル: | B₂cat₂-Mediated Reduction of Sulfoxides to Sulfides |
| 著者: | Takahashi, Fumiya Nogi, Keisuke Yorimitsu, Hideki    https://orcid.org/0000-0002-0153-1888 (unconfirmed) |
| 著者名の別形: | 高橋, 郁也 野木, 馨介 依光, 英樹 |
| キーワード: | Bis(catecholato)diboron Chemoselectivity Reduction Sulfide Sulfoxide |
| 発行日: | 25-May-2020 |
| 出版者: | Wiley |
| 誌名: | European Journal of Organic Chemistry |
| 巻: | 2020 |
| 開始ページ: | 3009 |
| 終了ページ: | 3012 |
| 抄録: | An efficient and operationally simple method for the reduction of sulfoxides to sulfides has been developed using bis(catecholato)diboron (B₂cat₂) as a reducing agent. The present method accommodates various functional groups which are generally prone to reduction: halides, alkynes, carbonyls, nitriles, and heterocycles are totally intact, and only sulfoxide moieties undergo reduction chemoselectively. Moreover, the remaining diboron and the resulting boron‐containing wastes are readily removable, the practicality of this protocol being thus demonstrated. |
| 著作権等: | This is the peer reviewed version of the following article: Takahashi, F., Nogi, K. and Yorimitsu, H. (2020), B2cat2‐Mediated Reduction of Sulfoxides to Sulfides. Eur. J. Org. Chem., 2020: 3009-3012, which has been published in final form at https://doi.org/10.1002/ejoc.202000222. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. The full-text file will be made open to the public on 19 March 2021 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/250999 |
| DOI(出版社版): | 10.1002/ejoc.202000222 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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